Fitoextração e Bioacessibilidade de As, Cd, Pb E Zn em solos contaminados por resíduos metalúrgicos
Autor(a) principal: | |
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Data de Publicação: | 2016 |
Tipo de documento: | Dissertação |
Idioma: | por |
Título da fonte: | Biblioteca Digital de Teses e Dissertações da UFRPE |
Texto Completo: | http://www.tede2.ufrpe.br:8080/tede2/handle/tede2/5363 |
Resumo: | The generation of residues through mining is a potential risk of contamination of soil, water, plants and animals. For decades, the municipality of Santo Amaro da Purificação - BA has suffered the impacts caused by improper and inadequate release of thousands of tons of siderurgy slag contaminated mainly by Cd and Pb, and exposure of these contaminants to the population through the distribution of this material to landfills in squares, streets and homes. The city is now known for presenting the greatest human contamination by Pb in the world. In order to understand the impacts of residues in soil and the risk of human contamination from contaminated soil, this study investigated the phytoextraction by maize and castor as a technique for remediation of these soils and to evaluate the risk of human contamination by heavy metals added to the soil by waste. For this, an experiment was conducted in a greenhouse with the use of the two plant species and soil application of inducing agents Phytoextraction (NTA and citric acid). After the cultivation, they evaluated the levels of As, Cd, Pb and Zn in soil and plant to evaluate the potential remediation technique. Fractionation of metals in the soil and bioaccessibility tests to assess the risk of contamination were also performed. The application of chelating agents citric acid and NTA and increased absorption of heavy metals by maize and castor. Despite the removal of metals by application of citric acid is smaller, this is more suitable due to its higher degradability and assist in inhibiting the phytotoxicity of the metals. Corn showed better phytoextraction ability to As, Cd, Pb and Zn in the study. The castor, despite having high concentrations of metals translocated, presented accumulation in roots, can be used as phytoextabiletion plant and generating economic benefits for the production of non-edible vegetable oil. The presence of metal contaminants from the ground indiscriminately in the area of the former COBRAC presents a high risk of contamination of humans through exposure of metals. |
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NASCIMENTO, Clístenes Williams Araújo doBIONDI, Caroline MirandaFRACETTO, Felipe José Curyhttp://lattes.cnpq.br/5033735462082389SILVA, William Ramos da2016-08-17T11:10:50Z2016-07-29SILVA, William Ramos da. Fitoextração e Bioacessibilidade de As, Cd, Pb E Zn em solos contaminados por resíduos metalúrgicos. 2016. 58 f. Dissertação (Programa de Pós-Graduação em Ciência do Solo) - Universidade Federal Rural de Pernambuco, Recife.http://www.tede2.ufrpe.br:8080/tede2/handle/tede2/5363The generation of residues through mining is a potential risk of contamination of soil, water, plants and animals. For decades, the municipality of Santo Amaro da Purificação - BA has suffered the impacts caused by improper and inadequate release of thousands of tons of siderurgy slag contaminated mainly by Cd and Pb, and exposure of these contaminants to the population through the distribution of this material to landfills in squares, streets and homes. The city is now known for presenting the greatest human contamination by Pb in the world. In order to understand the impacts of residues in soil and the risk of human contamination from contaminated soil, this study investigated the phytoextraction by maize and castor as a technique for remediation of these soils and to evaluate the risk of human contamination by heavy metals added to the soil by waste. For this, an experiment was conducted in a greenhouse with the use of the two plant species and soil application of inducing agents Phytoextraction (NTA and citric acid). After the cultivation, they evaluated the levels of As, Cd, Pb and Zn in soil and plant to evaluate the potential remediation technique. Fractionation of metals in the soil and bioaccessibility tests to assess the risk of contamination were also performed. The application of chelating agents citric acid and NTA and increased absorption of heavy metals by maize and castor. Despite the removal of metals by application of citric acid is smaller, this is more suitable due to its higher degradability and assist in inhibiting the phytotoxicity of the metals. Corn showed better phytoextraction ability to As, Cd, Pb and Zn in the study. The castor, despite having high concentrations of metals translocated, presented accumulation in roots, can be used as phytoextabiletion plant and generating economic benefits for the production of non-edible vegetable oil. The presence of metal contaminants from the ground indiscriminately in the area of the former COBRAC presents a high risk of contamination of humans through exposure of metals.A geração de resíduos através da mineração representa um risco potencial de contaminação do solo, recursos hídricos, plantas e animais. Durante décadas, o município de Santo Amaro da Purificação – BA tem sofrido os impactos causados pela liberação indevida e inadequada de milhares de toneladas de escória de siderurgia, contaminada principalmente por Cd e Pb, e pela exposição destes contaminantes à população através da distribuição desse material para aterros em praças, ruas e residências. A cidade hoje é conhecida por apresentar a maior contaminação humana por Pb no mundo. Com a intenção de entender os impactos causados pelos resíduos nos solos, bem como os riscos de contaminação humana por solo contaminado, o presente trabalho objetivou estudar a fitoextração por milho e mamona como uma técnica para remediação desses solos e avaliar o risco de contaminação humana pelos metais pesados adicionados ao solo pelos resíduos. Para isto, foi realizado um experimento em casa de vegetação com a utilização das duas espécies vegetais e aplicação ao solo de agentes indutores da fitoextração (ácido cítrico e NTA). Após o período de cultivo, foram avaliados os teores de As, Cd, Pb e Zn no solo e na planta para avaliar o potencial da técnica de remediação. Fracionamento dos metais no solo e testes de bioacessibilidade para avaliar o risco de contaminação foram também efetuados. A aplicação dos agentes quelantes ácido cítrico e NTA aumentou a absorção de metais pesados por milho e mamona. Apesar da remoção dos metais com aplicação de ácido cítrico ser menor, este é mais indicado por apresentar maior degradabilidade e auxiliar na inibição da fitotoxicidade dos metais. O milho apresentou melhor capacidade fitoextratora para As, Cd, Pb e Zn no solo em estudo. A mamona, apesar de não ter translocado concentrações altas dos metais, apresentou acúmulo nas raízes, podendo ser utilizada como planta fitoestabilizadora e geradora de benefícios econômicos pela produção de óleo vegetal não comestível. A presença de metais contaminantes do solo de forma indiscriminada na área da antiga COBRAC apresenta risco elevado de contaminação dos seres humanos através da exposição dos metais.Submitted by (lucia.rodrigues@ufrpe.br) on 2016-08-17T11:10:50Z No. of bitstreams: 1 William Ramos da Silva.pdf: 1949081 bytes, checksum: c61378bed7319d565cc47084de59c025 (MD5)Made available in DSpace on 2016-08-17T11:10:50Z (GMT). No. of bitstreams: 1 William Ramos da Silva.pdf: 1949081 bytes, checksum: c61378bed7319d565cc47084de59c025 (MD5) Previous issue date: 2016-07-29Conselho Nacional de Pesquisa e Desenvolvimento Científico e Tecnológico - CNPqapplication/pdfporUniversidade Federal Rural de PernambucoPrograma de Pós-Graduação em Ciência do SoloUFRPEBrasilDepartamento de AgronomiaFitoextraçãoContaminação do soloMetal pesadoSoilContaminationHeavy metalsChelating agentsAGRONOMIA::CIENCIA DO SOLOFitoextração e Bioacessibilidade de As, Cd, Pb E Zn em solos contaminados por resíduos metalúrgicosinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/masterThesis8551734419043507650600600600600-6800553879972229205-5919840527232375671-2555911436985713659info:eu-repo/semantics/openAccessreponame:Biblioteca Digital de Teses e Dissertações da UFRPEinstname:Universidade Federal Rural de Pernambuco (UFRPE)instacron:UFRPELICENSElicense.txtlicense.txttext/plain; charset=utf-82165http://www.tede2.ufrpe.br:8080/tede2/bitstream/tede2/5363/1/license.txtbd3efa91386c1718a7f26a329fdcb468MD51ORIGINALWilliam Ramos da Silva.pdfWilliam Ramos da Silva.pdfapplication/pdf1949081http://www.tede2.ufrpe.br:8080/tede2/bitstream/tede2/5363/2/William+Ramos+da+Silva.pdfc61378bed7319d565cc47084de59c025MD52tede2/53632019-07-12 10:08:22.488oai:tede2: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Biblioteca Digital de Teses e Dissertaçõeshttp://www.tede2.ufrpe.br:8080/tede/PUBhttp://www.tede2.ufrpe.br:8080/oai/requestbdtd@ufrpe.br ||bdtd@ufrpe.bropendoar:2024-05-28T12:32:57.392738Biblioteca Digital de Teses e Dissertações da UFRPE - Universidade Federal Rural de Pernambuco (UFRPE)false |
dc.title.por.fl_str_mv |
Fitoextração e Bioacessibilidade de As, Cd, Pb E Zn em solos contaminados por resíduos metalúrgicos |
title |
Fitoextração e Bioacessibilidade de As, Cd, Pb E Zn em solos contaminados por resíduos metalúrgicos |
spellingShingle |
Fitoextração e Bioacessibilidade de As, Cd, Pb E Zn em solos contaminados por resíduos metalúrgicos SILVA, William Ramos da Fitoextração Contaminação do solo Metal pesado Soil Contamination Heavy metals Chelating agents AGRONOMIA::CIENCIA DO SOLO |
title_short |
Fitoextração e Bioacessibilidade de As, Cd, Pb E Zn em solos contaminados por resíduos metalúrgicos |
title_full |
Fitoextração e Bioacessibilidade de As, Cd, Pb E Zn em solos contaminados por resíduos metalúrgicos |
title_fullStr |
Fitoextração e Bioacessibilidade de As, Cd, Pb E Zn em solos contaminados por resíduos metalúrgicos |
title_full_unstemmed |
Fitoextração e Bioacessibilidade de As, Cd, Pb E Zn em solos contaminados por resíduos metalúrgicos |
title_sort |
Fitoextração e Bioacessibilidade de As, Cd, Pb E Zn em solos contaminados por resíduos metalúrgicos |
author |
SILVA, William Ramos da |
author_facet |
SILVA, William Ramos da |
author_role |
author |
dc.contributor.advisor1.fl_str_mv |
NASCIMENTO, Clístenes Williams Araújo do |
dc.contributor.referee1.fl_str_mv |
BIONDI, Caroline Miranda |
dc.contributor.referee2.fl_str_mv |
FRACETTO, Felipe José Cury |
dc.contributor.authorLattes.fl_str_mv |
http://lattes.cnpq.br/5033735462082389 |
dc.contributor.author.fl_str_mv |
SILVA, William Ramos da |
contributor_str_mv |
NASCIMENTO, Clístenes Williams Araújo do BIONDI, Caroline Miranda FRACETTO, Felipe José Cury |
dc.subject.por.fl_str_mv |
Fitoextração Contaminação do solo Metal pesado |
topic |
Fitoextração Contaminação do solo Metal pesado Soil Contamination Heavy metals Chelating agents AGRONOMIA::CIENCIA DO SOLO |
dc.subject.eng.fl_str_mv |
Soil Contamination Heavy metals Chelating agents |
dc.subject.cnpq.fl_str_mv |
AGRONOMIA::CIENCIA DO SOLO |
description |
The generation of residues through mining is a potential risk of contamination of soil, water, plants and animals. For decades, the municipality of Santo Amaro da Purificação - BA has suffered the impacts caused by improper and inadequate release of thousands of tons of siderurgy slag contaminated mainly by Cd and Pb, and exposure of these contaminants to the population through the distribution of this material to landfills in squares, streets and homes. The city is now known for presenting the greatest human contamination by Pb in the world. In order to understand the impacts of residues in soil and the risk of human contamination from contaminated soil, this study investigated the phytoextraction by maize and castor as a technique for remediation of these soils and to evaluate the risk of human contamination by heavy metals added to the soil by waste. For this, an experiment was conducted in a greenhouse with the use of the two plant species and soil application of inducing agents Phytoextraction (NTA and citric acid). After the cultivation, they evaluated the levels of As, Cd, Pb and Zn in soil and plant to evaluate the potential remediation technique. Fractionation of metals in the soil and bioaccessibility tests to assess the risk of contamination were also performed. The application of chelating agents citric acid and NTA and increased absorption of heavy metals by maize and castor. Despite the removal of metals by application of citric acid is smaller, this is more suitable due to its higher degradability and assist in inhibiting the phytotoxicity of the metals. Corn showed better phytoextraction ability to As, Cd, Pb and Zn in the study. The castor, despite having high concentrations of metals translocated, presented accumulation in roots, can be used as phytoextabiletion plant and generating economic benefits for the production of non-edible vegetable oil. The presence of metal contaminants from the ground indiscriminately in the area of the former COBRAC presents a high risk of contamination of humans through exposure of metals. |
publishDate |
2016 |
dc.date.accessioned.fl_str_mv |
2016-08-17T11:10:50Z |
dc.date.issued.fl_str_mv |
2016-07-29 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/masterThesis |
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masterThesis |
status_str |
publishedVersion |
dc.identifier.citation.fl_str_mv |
SILVA, William Ramos da. Fitoextração e Bioacessibilidade de As, Cd, Pb E Zn em solos contaminados por resíduos metalúrgicos. 2016. 58 f. Dissertação (Programa de Pós-Graduação em Ciência do Solo) - Universidade Federal Rural de Pernambuco, Recife. |
dc.identifier.uri.fl_str_mv |
http://www.tede2.ufrpe.br:8080/tede2/handle/tede2/5363 |
identifier_str_mv |
SILVA, William Ramos da. Fitoextração e Bioacessibilidade de As, Cd, Pb E Zn em solos contaminados por resíduos metalúrgicos. 2016. 58 f. Dissertação (Programa de Pós-Graduação em Ciência do Solo) - Universidade Federal Rural de Pernambuco, Recife. |
url |
http://www.tede2.ufrpe.br:8080/tede2/handle/tede2/5363 |
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Universidade Federal Rural de Pernambuco |
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