Effect of Starch Laurate Addition on the Properties of Mango Kernel Starch Films
Autor(a) principal: | |
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Data de Publicação: | 2021 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Materials research (São Carlos. Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392021000300213 |
Resumo: | Abstract In this work, starch obtained from mango kernel seeds was applied in the preparation of films in combination with its hydrophobic derivatives. Chemical modification of starch was carried out at two different concentrations of vinyl laurate, in dimethyl sulfoxide, under basic catalysis. The degrees of substitution of the starch laurates were 2.4 and 0.3, respectively. None of the products formed films when dispersed in water. However, blends of starch/starch laurate (degree of substitution = 0.3) formed films after microfluidization of their aqueous suspensions. The blends with up to 15% wt of starch laurate (degree of substitution = 0.3) resulted in films of higher elongation at break, higher opacity and lower tensile strength and elastic modulus. The microfluidization of biopolymer suspensions was crucial to obtain films with lower water vapor permeability. X-ray diffraction results corroborated to the mechanical properties of the films, showing that the incorporation of starch laurate reduced the starch films crystallinity. |
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Materials research (São Carlos. Online) |
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|
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Effect of Starch Laurate Addition on the Properties of Mango Kernel Starch Filmsindustrial wastestarch esterbiodegradable filmsmicrofluidizationAbstract In this work, starch obtained from mango kernel seeds was applied in the preparation of films in combination with its hydrophobic derivatives. Chemical modification of starch was carried out at two different concentrations of vinyl laurate, in dimethyl sulfoxide, under basic catalysis. The degrees of substitution of the starch laurates were 2.4 and 0.3, respectively. None of the products formed films when dispersed in water. However, blends of starch/starch laurate (degree of substitution = 0.3) formed films after microfluidization of their aqueous suspensions. The blends with up to 15% wt of starch laurate (degree of substitution = 0.3) resulted in films of higher elongation at break, higher opacity and lower tensile strength and elastic modulus. The microfluidization of biopolymer suspensions was crucial to obtain films with lower water vapor permeability. X-ray diffraction results corroborated to the mechanical properties of the films, showing that the incorporation of starch laurate reduced the starch films crystallinity.ABM, ABC, ABPol2021-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392021000300213Materials Research v.24 n.3 2021reponame:Materials research (São Carlos. Online)instname:Universidade Federal de São Carlos (UFSCAR)instacron:ABM ABC ABPOL10.1590/1980-5373-mr-2020-0331info:eu-repo/semantics/openAccessCarvalho,Laura Gabriela Gurgel deMarques,Nívia do NascimentoFernandes,Rafael da SilvaVilletti,Marcos AntônioSouza Filho,Men de Sá Moreira deBalaban,Rosangela de Carvalhoeng2021-04-14T00:00:00Zoai:scielo:S1516-14392021000300213Revistahttp://www.scielo.br/mrPUBhttps://old.scielo.br/oai/scielo-oai.phpdedz@power.ufscar.br1980-53731516-1439opendoar:2021-04-14T00:00Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR)false |
dc.title.none.fl_str_mv |
Effect of Starch Laurate Addition on the Properties of Mango Kernel Starch Films |
title |
Effect of Starch Laurate Addition on the Properties of Mango Kernel Starch Films |
spellingShingle |
Effect of Starch Laurate Addition on the Properties of Mango Kernel Starch Films Carvalho,Laura Gabriela Gurgel de industrial waste starch ester biodegradable films microfluidization |
title_short |
Effect of Starch Laurate Addition on the Properties of Mango Kernel Starch Films |
title_full |
Effect of Starch Laurate Addition on the Properties of Mango Kernel Starch Films |
title_fullStr |
Effect of Starch Laurate Addition on the Properties of Mango Kernel Starch Films |
title_full_unstemmed |
Effect of Starch Laurate Addition on the Properties of Mango Kernel Starch Films |
title_sort |
Effect of Starch Laurate Addition on the Properties of Mango Kernel Starch Films |
author |
Carvalho,Laura Gabriela Gurgel de |
author_facet |
Carvalho,Laura Gabriela Gurgel de Marques,Nívia do Nascimento Fernandes,Rafael da Silva Villetti,Marcos Antônio Souza Filho,Men de Sá Moreira de Balaban,Rosangela de Carvalho |
author_role |
author |
author2 |
Marques,Nívia do Nascimento Fernandes,Rafael da Silva Villetti,Marcos Antônio Souza Filho,Men de Sá Moreira de Balaban,Rosangela de Carvalho |
author2_role |
author author author author author |
dc.contributor.author.fl_str_mv |
Carvalho,Laura Gabriela Gurgel de Marques,Nívia do Nascimento Fernandes,Rafael da Silva Villetti,Marcos Antônio Souza Filho,Men de Sá Moreira de Balaban,Rosangela de Carvalho |
dc.subject.por.fl_str_mv |
industrial waste starch ester biodegradable films microfluidization |
topic |
industrial waste starch ester biodegradable films microfluidization |
description |
Abstract In this work, starch obtained from mango kernel seeds was applied in the preparation of films in combination with its hydrophobic derivatives. Chemical modification of starch was carried out at two different concentrations of vinyl laurate, in dimethyl sulfoxide, under basic catalysis. The degrees of substitution of the starch laurates were 2.4 and 0.3, respectively. None of the products formed films when dispersed in water. However, blends of starch/starch laurate (degree of substitution = 0.3) formed films after microfluidization of their aqueous suspensions. The blends with up to 15% wt of starch laurate (degree of substitution = 0.3) resulted in films of higher elongation at break, higher opacity and lower tensile strength and elastic modulus. The microfluidization of biopolymer suspensions was crucial to obtain films with lower water vapor permeability. X-ray diffraction results corroborated to the mechanical properties of the films, showing that the incorporation of starch laurate reduced the starch films crystallinity. |
publishDate |
2021 |
dc.date.none.fl_str_mv |
2021-01-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392021000300213 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392021000300213 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/1980-5373-mr-2020-0331 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
ABM, ABC, ABPol |
publisher.none.fl_str_mv |
ABM, ABC, ABPol |
dc.source.none.fl_str_mv |
Materials Research v.24 n.3 2021 reponame:Materials research (São Carlos. Online) instname:Universidade Federal de São Carlos (UFSCAR) instacron:ABM ABC ABPOL |
instname_str |
Universidade Federal de São Carlos (UFSCAR) |
instacron_str |
ABM ABC ABPOL |
institution |
ABM ABC ABPOL |
reponame_str |
Materials research (São Carlos. Online) |
collection |
Materials research (São Carlos. Online) |
repository.name.fl_str_mv |
Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR) |
repository.mail.fl_str_mv |
dedz@power.ufscar.br |
_version_ |
1754212678630375424 |