An NMR tool for cyclodextrin selection in enantiomeric resolution by high-performance liquid chromatography.

Detalhes bibliográficos
Autor(a) principal: LAVERDE JÚNIOR, A.
Data de Publicação: 2002
Outros Autores: CONCEIÇÃO, G. J. A. da, QUEIROZ, S. C. do N. de, FUJIWARA, F. Y., MARSAIOLI, A. J.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da EMBRAPA (Repository Open Access to Scientific Information from EMBRAPA - Alice)
Texto Completo: http://www.alice.cnptia.embrapa.br/alice/handle/doc/15077
Resumo: Complexation-induced chemical shifts and diffusion coefficients (HR-DOSY) of enantiomers with native and derivatized cyclodextrins were used for calculations of the apparent binding constants of three cyclohexanone inclusion complexes. Correlations between these data and high-performance liquid chromatography were established, revealing that this approach can be applied as an alternative method to predict enantiomeric discrimination.
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spelling An NMR tool for cyclodextrin selection in enantiomeric resolution by high-performance liquid chromatography.CromatografiaAnálise químicaComplexation-induced chemical shifts and diffusion coefficients (HR-DOSY) of enantiomers with native and derivatized cyclodextrins were used for calculations of the apparent binding constants of three cyclohexanone inclusion complexes. Correlations between these data and high-performance liquid chromatography were established, revealing that this approach can be applied as an alternative method to predict enantiomeric discrimination.A. LAVERDE JÚNIOR, IQ/Unicamp; G. J. A. da CONCEIÇÃO, IQ/Unicamp; SONIA CLAUDIA DO N DE QUEIROZ, CNPMA; F. Y. FUJIWARA, IQ/Unicamp; A. J. MARSAIOLI, IQ/Unicamp.LAVERDE JÚNIOR, A.CONCEIÇÃO, G. J. A. daQUEIROZ, S. C. do N. deFUJIWARA, F. Y.MARSAIOLI, A. J.2017-09-19T00:12:49Z2017-09-19T00:12:49Z2006-10-0420022018-08-01T11:11:11Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleMagnetic Ressonance in Chemistry, Chichester, v. 40, p. 433-442, 2002.http://www.alice.cnptia.embrapa.br/alice/handle/doc/15077enginfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da EMBRAPA (Repository Open Access to Scientific Information from EMBRAPA - Alice)instname:Empresa Brasileira de Pesquisa Agropecuária (Embrapa)instacron:EMBRAPA2017-09-19T00:12:49Zoai:www.alice.cnptia.embrapa.br:doc/15077Repositório InstitucionalPUBhttps://www.alice.cnptia.embrapa.br/oai/requestopendoar:21542017-09-19T00:12:49falseRepositório InstitucionalPUBhttps://www.alice.cnptia.embrapa.br/oai/requestcg-riaa@embrapa.bropendoar:21542017-09-19T00:12:49Repositório Institucional da EMBRAPA (Repository Open Access to Scientific Information from EMBRAPA - Alice) - Empresa Brasileira de Pesquisa Agropecuária (Embrapa)false
dc.title.none.fl_str_mv An NMR tool for cyclodextrin selection in enantiomeric resolution by high-performance liquid chromatography.
title An NMR tool for cyclodextrin selection in enantiomeric resolution by high-performance liquid chromatography.
spellingShingle An NMR tool for cyclodextrin selection in enantiomeric resolution by high-performance liquid chromatography.
LAVERDE JÚNIOR, A.
Cromatografia
Análise química
title_short An NMR tool for cyclodextrin selection in enantiomeric resolution by high-performance liquid chromatography.
title_full An NMR tool for cyclodextrin selection in enantiomeric resolution by high-performance liquid chromatography.
title_fullStr An NMR tool for cyclodextrin selection in enantiomeric resolution by high-performance liquid chromatography.
title_full_unstemmed An NMR tool for cyclodextrin selection in enantiomeric resolution by high-performance liquid chromatography.
title_sort An NMR tool for cyclodextrin selection in enantiomeric resolution by high-performance liquid chromatography.
author LAVERDE JÚNIOR, A.
author_facet LAVERDE JÚNIOR, A.
CONCEIÇÃO, G. J. A. da
QUEIROZ, S. C. do N. de
FUJIWARA, F. Y.
MARSAIOLI, A. J.
author_role author
author2 CONCEIÇÃO, G. J. A. da
QUEIROZ, S. C. do N. de
FUJIWARA, F. Y.
MARSAIOLI, A. J.
author2_role author
author
author
author
dc.contributor.none.fl_str_mv A. LAVERDE JÚNIOR, IQ/Unicamp; G. J. A. da CONCEIÇÃO, IQ/Unicamp; SONIA CLAUDIA DO N DE QUEIROZ, CNPMA; F. Y. FUJIWARA, IQ/Unicamp; A. J. MARSAIOLI, IQ/Unicamp.
dc.contributor.author.fl_str_mv LAVERDE JÚNIOR, A.
CONCEIÇÃO, G. J. A. da
QUEIROZ, S. C. do N. de
FUJIWARA, F. Y.
MARSAIOLI, A. J.
dc.subject.por.fl_str_mv Cromatografia
Análise química
topic Cromatografia
Análise química
description Complexation-induced chemical shifts and diffusion coefficients (HR-DOSY) of enantiomers with native and derivatized cyclodextrins were used for calculations of the apparent binding constants of three cyclohexanone inclusion complexes. Correlations between these data and high-performance liquid chromatography were established, revealing that this approach can be applied as an alternative method to predict enantiomeric discrimination.
publishDate 2002
dc.date.none.fl_str_mv 2002
2006-10-04
2017-09-19T00:12:49Z
2017-09-19T00:12:49Z
2018-08-01T11:11:11Z
dc.type.driver.fl_str_mv info:eu-repo/semantics/publishedVersion
info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv Magnetic Ressonance in Chemistry, Chichester, v. 40, p. 433-442, 2002.
http://www.alice.cnptia.embrapa.br/alice/handle/doc/15077
identifier_str_mv Magnetic Ressonance in Chemistry, Chichester, v. 40, p. 433-442, 2002.
url http://www.alice.cnptia.embrapa.br/alice/handle/doc/15077
dc.language.iso.fl_str_mv eng
language eng
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.source.none.fl_str_mv reponame:Repositório Institucional da EMBRAPA (Repository Open Access to Scientific Information from EMBRAPA - Alice)
instname:Empresa Brasileira de Pesquisa Agropecuária (Embrapa)
instacron:EMBRAPA
instname_str Empresa Brasileira de Pesquisa Agropecuária (Embrapa)
instacron_str EMBRAPA
institution EMBRAPA
reponame_str Repositório Institucional da EMBRAPA (Repository Open Access to Scientific Information from EMBRAPA - Alice)
collection Repositório Institucional da EMBRAPA (Repository Open Access to Scientific Information from EMBRAPA - Alice)
repository.name.fl_str_mv Repositório Institucional da EMBRAPA (Repository Open Access to Scientific Information from EMBRAPA - Alice) - Empresa Brasileira de Pesquisa Agropecuária (Embrapa)
repository.mail.fl_str_mv cg-riaa@embrapa.br
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