Bis{4-phenyl-1-[1-(pyridin-2-yl-[kappa]N)ethylidene]thiosemicarbazidato-[kappa]2N1,S}cadmium

Detalhes bibliográficos
Autor(a) principal: Fonseca, Alexandra de Souza
Data de Publicação: 2012
Outros Autores: Gervini, Vanessa Carratu, Bresolin, Leandro, Locatelli, Aline, Oliveira, Adriano Bof de
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da FURG (RI FURG)
Texto Completo: http://repositorio.furg.br/handle/1/4611
Resumo: The reaction of cadmium acetate dihydrate with 2-acetylpyridine (4-phenylthiosemicarbazone) yielded the title compound, [Cd(C14H13N4S)2]. The CdII atom is six-coordinated in a distorted octahedral environment by two deprotonated thiosemicarbazone ligands acting in a tridentate chelating mode through two N and one S atoms, forming metalla-rings. In the crystal, molecules are connected through inversion centers via pairs of N-H...S interactions, building a one-dimensional hydrogen-bonded polymer along [0-1-1].
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spelling Bis{4-phenyl-1-[1-(pyridin-2-yl-[kappa]N)ethylidene]thiosemicarbazidato-[kappa]2N1,S}cadmiumSingle-crystal X-ray studyT = 296 KMean (C–C) = 0.005 A˚R factor = 0.038wR factor = 0.080Data-to-parameter ratio = 22.6The reaction of cadmium acetate dihydrate with 2-acetylpyridine (4-phenylthiosemicarbazone) yielded the title compound, [Cd(C14H13N4S)2]. The CdII atom is six-coordinated in a distorted octahedral environment by two deprotonated thiosemicarbazone ligands acting in a tridentate chelating mode through two N and one S atoms, forming metalla-rings. In the crystal, molecules are connected through inversion centers via pairs of N-H...S interactions, building a one-dimensional hydrogen-bonded polymer along [0-1-1].2014-09-23T23:03:35Z2014-09-23T23:03:35Z2012info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfFONSECA, Alexandra de Souza et al. Bis{4-phenyl-1-[1-(pyridin-2-yl-[kappa]N)ethylidene]thiosemicarbazidato-[kappa]2N1,S}cadmium. Acta Crystallographica Section E, v. 68, n. 5, p. 635-636, 2012. Disponível em:<http://journals.iucr.org/e/issues/2012/05/00/bt5877/bt5877.pdf>. Acesso em: 23 set. 2014.1600-5368http://repositorio.furg.br/handle/1/461110.1107/S1600536812016558engFonseca, Alexandra de SouzaGervini, Vanessa CarratuBresolin, LeandroLocatelli, AlineOliveira, Adriano Bof deinfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da FURG (RI FURG)instname:Universidade Federal do Rio Grande (FURG)instacron:FURG2014-09-23T23:03:35Zoai:repositorio.furg.br:1/4611Repositório InstitucionalPUBhttps://repositorio.furg.br/oai/request || http://200.19.254.174/oai/requestopendoar:2014-09-23T23:03:35Repositório Institucional da FURG (RI FURG) - Universidade Federal do Rio Grande (FURG)false
dc.title.none.fl_str_mv Bis{4-phenyl-1-[1-(pyridin-2-yl-[kappa]N)ethylidene]thiosemicarbazidato-[kappa]2N1,S}cadmium
title Bis{4-phenyl-1-[1-(pyridin-2-yl-[kappa]N)ethylidene]thiosemicarbazidato-[kappa]2N1,S}cadmium
spellingShingle Bis{4-phenyl-1-[1-(pyridin-2-yl-[kappa]N)ethylidene]thiosemicarbazidato-[kappa]2N1,S}cadmium
Fonseca, Alexandra de Souza
Single-crystal X-ray study
T = 296 K
Mean (C–C) = 0.005 A˚
R factor = 0.038
wR factor = 0.080
Data-to-parameter ratio = 22.6
title_short Bis{4-phenyl-1-[1-(pyridin-2-yl-[kappa]N)ethylidene]thiosemicarbazidato-[kappa]2N1,S}cadmium
title_full Bis{4-phenyl-1-[1-(pyridin-2-yl-[kappa]N)ethylidene]thiosemicarbazidato-[kappa]2N1,S}cadmium
title_fullStr Bis{4-phenyl-1-[1-(pyridin-2-yl-[kappa]N)ethylidene]thiosemicarbazidato-[kappa]2N1,S}cadmium
title_full_unstemmed Bis{4-phenyl-1-[1-(pyridin-2-yl-[kappa]N)ethylidene]thiosemicarbazidato-[kappa]2N1,S}cadmium
title_sort Bis{4-phenyl-1-[1-(pyridin-2-yl-[kappa]N)ethylidene]thiosemicarbazidato-[kappa]2N1,S}cadmium
author Fonseca, Alexandra de Souza
author_facet Fonseca, Alexandra de Souza
Gervini, Vanessa Carratu
Bresolin, Leandro
Locatelli, Aline
Oliveira, Adriano Bof de
author_role author
author2 Gervini, Vanessa Carratu
Bresolin, Leandro
Locatelli, Aline
Oliveira, Adriano Bof de
author2_role author
author
author
author
dc.contributor.author.fl_str_mv Fonseca, Alexandra de Souza
Gervini, Vanessa Carratu
Bresolin, Leandro
Locatelli, Aline
Oliveira, Adriano Bof de
dc.subject.por.fl_str_mv Single-crystal X-ray study
T = 296 K
Mean (C–C) = 0.005 A˚
R factor = 0.038
wR factor = 0.080
Data-to-parameter ratio = 22.6
topic Single-crystal X-ray study
T = 296 K
Mean (C–C) = 0.005 A˚
R factor = 0.038
wR factor = 0.080
Data-to-parameter ratio = 22.6
description The reaction of cadmium acetate dihydrate with 2-acetylpyridine (4-phenylthiosemicarbazone) yielded the title compound, [Cd(C14H13N4S)2]. The CdII atom is six-coordinated in a distorted octahedral environment by two deprotonated thiosemicarbazone ligands acting in a tridentate chelating mode through two N and one S atoms, forming metalla-rings. In the crystal, molecules are connected through inversion centers via pairs of N-H...S interactions, building a one-dimensional hydrogen-bonded polymer along [0-1-1].
publishDate 2012
dc.date.none.fl_str_mv 2012
2014-09-23T23:03:35Z
2014-09-23T23:03:35Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv FONSECA, Alexandra de Souza et al. Bis{4-phenyl-1-[1-(pyridin-2-yl-[kappa]N)ethylidene]thiosemicarbazidato-[kappa]2N1,S}cadmium. Acta Crystallographica Section E, v. 68, n. 5, p. 635-636, 2012. Disponível em:<http://journals.iucr.org/e/issues/2012/05/00/bt5877/bt5877.pdf>. Acesso em: 23 set. 2014.
1600-5368
http://repositorio.furg.br/handle/1/4611
10.1107/S1600536812016558
identifier_str_mv FONSECA, Alexandra de Souza et al. Bis{4-phenyl-1-[1-(pyridin-2-yl-[kappa]N)ethylidene]thiosemicarbazidato-[kappa]2N1,S}cadmium. Acta Crystallographica Section E, v. 68, n. 5, p. 635-636, 2012. Disponível em:<http://journals.iucr.org/e/issues/2012/05/00/bt5877/bt5877.pdf>. Acesso em: 23 set. 2014.
1600-5368
10.1107/S1600536812016558
url http://repositorio.furg.br/handle/1/4611
dc.language.iso.fl_str_mv eng
language eng
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:Repositório Institucional da FURG (RI FURG)
instname:Universidade Federal do Rio Grande (FURG)
instacron:FURG
instname_str Universidade Federal do Rio Grande (FURG)
instacron_str FURG
institution FURG
reponame_str Repositório Institucional da FURG (RI FURG)
collection Repositório Institucional da FURG (RI FURG)
repository.name.fl_str_mv Repositório Institucional da FURG (RI FURG) - Universidade Federal do Rio Grande (FURG)
repository.mail.fl_str_mv
_version_ 1813187272656289792

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