[1-(5-Bromo-2-oxidobenzylidene)thiosemicarbazidato-[kappa]3O,N1,S](pyridine-[kappa]N)nickel(II)

Detalhes bibliográficos
Autor(a) principal: Pederzolli, Fernanda Rosi Soares
Data de Publicação: 2012
Outros Autores: Bresolin, Leandro, Beck, Johannes, Daniels, Jorg, Oliveira, Adriano Bof de
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da FURG (RI FURG)
Texto Completo: http://repositorio.furg.br/handle/1/4612
Resumo: The reaction of 5-bromosalicylaldehyde thiosemicarbazone with nickel acetate tetrahydrate and pyridine yielded the title compound, [Ni(C8H6BrN3OS)(C5H5N)]. The NiII atom is four-coordinated in a square-planar environment by one deprotonated dianionic thiosemicarbazone ligand, acting in a tridentate chelating mode through N, O and S atoms forming two metalla-rings, and by one pyridine molecule. The complex molecules are linked into dimers by pairs of centrosymmetrical N-H...N interactions. In addition, molecules are connected through intermolecular Br...Br interactions [3.545 (1) Å], forming chains along the b-axis direction.
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spelling [1-(5-Bromo-2-oxidobenzylidene)thiosemicarbazidato-[kappa]3O,N1,S](pyridine-[kappa]N)nickel(II)Single-crystal X-ray studyT = 293 KMean (C–C) = 0.004 A˚R factor = 0.031wR factor = 0.083Data-to-parameter ratio = 17.0The reaction of 5-bromosalicylaldehyde thiosemicarbazone with nickel acetate tetrahydrate and pyridine yielded the title compound, [Ni(C8H6BrN3OS)(C5H5N)]. The NiII atom is four-coordinated in a square-planar environment by one deprotonated dianionic thiosemicarbazone ligand, acting in a tridentate chelating mode through N, O and S atoms forming two metalla-rings, and by one pyridine molecule. The complex molecules are linked into dimers by pairs of centrosymmetrical N-H...N interactions. In addition, molecules are connected through intermolecular Br...Br interactions [3.545 (1) Å], forming chains along the b-axis direction.2014-09-23T23:30:37Z2014-09-23T23:30:37Z2012info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfPEDERZOLLI, Fernanda Rosi Soares et al. [1-(5-Bromo-2-oxidobenzylidene)thiosemicarbazidato-[kappa]3O,N1,S](pyridine-[kappa]N)nickel(II). Acta Crystallographica Section E, v. 68, n. 9, p. 1138-1138, 2012. Disponível em: <http://journals.iucr.org/e/issues/2012/09/00/zl2486/zl2486.pdf>. Acesso em: 23 set. 2014.1600-5368http://repositorio.furg.br/handle/1/461210.1107/S1600536812028917engPederzolli, Fernanda Rosi SoaresBresolin, LeandroBeck, JohannesDaniels, JorgOliveira, Adriano Bof deinfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da FURG (RI FURG)instname:Universidade Federal do Rio Grande (FURG)instacron:FURG2014-09-23T23:30:37Zoai:repositorio.furg.br:1/4612Repositório InstitucionalPUBhttps://repositorio.furg.br/oai/request || http://200.19.254.174/oai/requestopendoar:2014-09-23T23:30:37Repositório Institucional da FURG (RI FURG) - Universidade Federal do Rio Grande (FURG)false
dc.title.none.fl_str_mv [1-(5-Bromo-2-oxidobenzylidene)thiosemicarbazidato-[kappa]3O,N1,S](pyridine-[kappa]N)nickel(II)
title [1-(5-Bromo-2-oxidobenzylidene)thiosemicarbazidato-[kappa]3O,N1,S](pyridine-[kappa]N)nickel(II)
spellingShingle [1-(5-Bromo-2-oxidobenzylidene)thiosemicarbazidato-[kappa]3O,N1,S](pyridine-[kappa]N)nickel(II)
Pederzolli, Fernanda Rosi Soares
Single-crystal X-ray study
T = 293 K
Mean (C–C) = 0.004 A˚
R factor = 0.031
wR factor = 0.083
Data-to-parameter ratio = 17.0
title_short [1-(5-Bromo-2-oxidobenzylidene)thiosemicarbazidato-[kappa]3O,N1,S](pyridine-[kappa]N)nickel(II)
title_full [1-(5-Bromo-2-oxidobenzylidene)thiosemicarbazidato-[kappa]3O,N1,S](pyridine-[kappa]N)nickel(II)
title_fullStr [1-(5-Bromo-2-oxidobenzylidene)thiosemicarbazidato-[kappa]3O,N1,S](pyridine-[kappa]N)nickel(II)
title_full_unstemmed [1-(5-Bromo-2-oxidobenzylidene)thiosemicarbazidato-[kappa]3O,N1,S](pyridine-[kappa]N)nickel(II)
title_sort [1-(5-Bromo-2-oxidobenzylidene)thiosemicarbazidato-[kappa]3O,N1,S](pyridine-[kappa]N)nickel(II)
author Pederzolli, Fernanda Rosi Soares
author_facet Pederzolli, Fernanda Rosi Soares
Bresolin, Leandro
Beck, Johannes
Daniels, Jorg
Oliveira, Adriano Bof de
author_role author
author2 Bresolin, Leandro
Beck, Johannes
Daniels, Jorg
Oliveira, Adriano Bof de
author2_role author
author
author
author
dc.contributor.author.fl_str_mv Pederzolli, Fernanda Rosi Soares
Bresolin, Leandro
Beck, Johannes
Daniels, Jorg
Oliveira, Adriano Bof de
dc.subject.por.fl_str_mv Single-crystal X-ray study
T = 293 K
Mean (C–C) = 0.004 A˚
R factor = 0.031
wR factor = 0.083
Data-to-parameter ratio = 17.0
topic Single-crystal X-ray study
T = 293 K
Mean (C–C) = 0.004 A˚
R factor = 0.031
wR factor = 0.083
Data-to-parameter ratio = 17.0
description The reaction of 5-bromosalicylaldehyde thiosemicarbazone with nickel acetate tetrahydrate and pyridine yielded the title compound, [Ni(C8H6BrN3OS)(C5H5N)]. The NiII atom is four-coordinated in a square-planar environment by one deprotonated dianionic thiosemicarbazone ligand, acting in a tridentate chelating mode through N, O and S atoms forming two metalla-rings, and by one pyridine molecule. The complex molecules are linked into dimers by pairs of centrosymmetrical N-H...N interactions. In addition, molecules are connected through intermolecular Br...Br interactions [3.545 (1) Å], forming chains along the b-axis direction.
publishDate 2012
dc.date.none.fl_str_mv 2012
2014-09-23T23:30:37Z
2014-09-23T23:30:37Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv PEDERZOLLI, Fernanda Rosi Soares et al. [1-(5-Bromo-2-oxidobenzylidene)thiosemicarbazidato-[kappa]3O,N1,S](pyridine-[kappa]N)nickel(II). Acta Crystallographica Section E, v. 68, n. 9, p. 1138-1138, 2012. Disponível em: <http://journals.iucr.org/e/issues/2012/09/00/zl2486/zl2486.pdf>. Acesso em: 23 set. 2014.
1600-5368
http://repositorio.furg.br/handle/1/4612
10.1107/S1600536812028917
identifier_str_mv PEDERZOLLI, Fernanda Rosi Soares et al. [1-(5-Bromo-2-oxidobenzylidene)thiosemicarbazidato-[kappa]3O,N1,S](pyridine-[kappa]N)nickel(II). Acta Crystallographica Section E, v. 68, n. 9, p. 1138-1138, 2012. Disponível em: <http://journals.iucr.org/e/issues/2012/09/00/zl2486/zl2486.pdf>. Acesso em: 23 set. 2014.
1600-5368
10.1107/S1600536812028917
url http://repositorio.furg.br/handle/1/4612
dc.language.iso.fl_str_mv eng
language eng
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:Repositório Institucional da FURG (RI FURG)
instname:Universidade Federal do Rio Grande (FURG)
instacron:FURG
instname_str Universidade Federal do Rio Grande (FURG)
instacron_str FURG
institution FURG
reponame_str Repositório Institucional da FURG (RI FURG)
collection Repositório Institucional da FURG (RI FURG)
repository.name.fl_str_mv Repositório Institucional da FURG (RI FURG) - Universidade Federal do Rio Grande (FURG)
repository.mail.fl_str_mv
_version_ 1822808139563532288

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