N-Methyl-2-(1-methyl-3-phenyl­prop-2-en-1-yl­idene)hydrazinecarbo­thio­amide

Detalhes bibliográficos
Autor(a) principal: Rocha, Fillipe Vieira [UNESP]
Data de Publicação: 2014
Outros Autores: Godoy Netto, Adelino Vieira de [UNESP]Beck, Johannes, Daniels, Jörg, Oliveira, Adriano Bof de
Tipo de documento: Artigo
Idioma: por
Título da fonte: Repositório Institucional da UNESP
Texto Completo: http://scripts.iucr.org/cgi-bin/paper?S1600536814013889
http://hdl.handle.net/11449/123551
Resumo: In the title compound, C12H15N3S, the mol­ecule deviates slightly from planarity, with a maximum deviation from the mean plane of the non-H atoms of 0.2756 (6) Å for the S atom and a torsion angle for the N-N-C-N fragment of -7.04 (16)°. In the crystal, mol­ecules are linked by N-H...S hydrogen-bond inter­actions, forming centrosymmetric dimers. Additionally, one weak intra­molecular N-H...N hydrogen-bond inter­action is observed. The crystal packing shows a herringbone arrangement viewed along the c axis.
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spelling N-Methyl-2-(1-methyl-3-phenyl­prop-2-en-1-yl­idene)hydrazinecarbo­thio­amidesingle-crystal X-ray studyT = 123 K; mean (C–C) = 0.002 A˚R factor = 0.031wR factor = 0.080data-to-parameter ratio = 13.6In the title compound, C12H15N3S, the mol­ecule deviates slightly from planarity, with a maximum deviation from the mean plane of the non-H atoms of 0.2756 (6) Å for the S atom and a torsion angle for the N-N-C-N fragment of -7.04 (16)°. In the crystal, mol­ecules are linked by N-H...S hydrogen-bond inter­actions, forming centrosymmetric dimers. Additionally, one weak intra­molecular N-H...N hydrogen-bond inter­action is observed. The crystal packing shows a herringbone arrangement viewed along the c axis.Universidade Estadual Paulista Júlio de Mesquita Filho, Departamento de Química Geral e Inorgânica, Instituto de Química de Araraquara, Araraquara, Rua Profesor Francisco Degni s/n, Quitandinha, CEP 14800-900, SP, BrasilUniversidade Estadual Paulista Júlio de Mesquita Filho, Departamento de Química Geral e Inorgânica, Instituto de Química de Araraquara, Araraquara, Rua Profesor Francisco Degni s/n, Quitandinha, CEP 14800-900, SP, BrasilUniversidade Estadual Paulista (Unesp)Universität BonnUniversidade Federal de Sergipe (UFS)Rocha, Fillipe Vieira [UNESP]Godoy Netto, Adelino Vieira de [UNESP]Beck, JohannesDaniels, JörgOliveira, Adriano Bof de2015-05-15T13:30:24Z2015-05-15T13:30:24Z2014info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleo800application/pdfhttp://scripts.iucr.org/cgi-bin/paper?S1600536814013889Acta Crystallographica. Section E, v. 70, n. 7, p. o800, 2014.1600-5368http://hdl.handle.net/11449/12355110.1107/s1600536814013889ISSN1600-5368-2014-70-07-o800.pdf7927677053650819Currículo Lattesreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPporActa Crystallographica. Section E0,138info:eu-repo/semantics/openAccess2023-11-09T06:10:33Zoai:repositorio.unesp.br:11449/123551Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462024-08-05T17:13:48.732904Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false
dc.title.none.fl_str_mv N-Methyl-2-(1-methyl-3-phenyl­prop-2-en-1-yl­idene)hydrazinecarbo­thio­amide
title N-Methyl-2-(1-methyl-3-phenyl­prop-2-en-1-yl­idene)hydrazinecarbo­thio­amide
spellingShingle N-Methyl-2-(1-methyl-3-phenyl­prop-2-en-1-yl­idene)hydrazinecarbo­thio­amide
Rocha, Fillipe Vieira [UNESP]
single-crystal X-ray study
T = 123 K; mean (C–C) = 0.002 A˚
R factor = 0.031
wR factor = 0.080
data-to-parameter ratio = 13.6
title_short N-Methyl-2-(1-methyl-3-phenyl­prop-2-en-1-yl­idene)hydrazinecarbo­thio­amide
title_full N-Methyl-2-(1-methyl-3-phenyl­prop-2-en-1-yl­idene)hydrazinecarbo­thio­amide
title_fullStr N-Methyl-2-(1-methyl-3-phenyl­prop-2-en-1-yl­idene)hydrazinecarbo­thio­amide
title_full_unstemmed N-Methyl-2-(1-methyl-3-phenyl­prop-2-en-1-yl­idene)hydrazinecarbo­thio­amide
title_sort N-Methyl-2-(1-methyl-3-phenyl­prop-2-en-1-yl­idene)hydrazinecarbo­thio­amide
author Rocha, Fillipe Vieira [UNESP]
author_facet Rocha, Fillipe Vieira [UNESP]
Godoy Netto, Adelino Vieira de [UNESP]Beck, Johannes
Daniels, Jörg
Oliveira, Adriano Bof de
author_role author
author2 Godoy Netto, Adelino Vieira de [UNESP]Beck, Johannes
Daniels, Jörg
Oliveira, Adriano Bof de
author2_role author
author
author
dc.contributor.none.fl_str_mv Universidade Estadual Paulista (Unesp)
Universität Bonn
Universidade Federal de Sergipe (UFS)
dc.contributor.author.fl_str_mv Rocha, Fillipe Vieira [UNESP]
Godoy Netto, Adelino Vieira de [UNESP]Beck, Johannes
Daniels, Jörg
Oliveira, Adriano Bof de
dc.subject.por.fl_str_mv single-crystal X-ray study
T = 123 K; mean (C–C) = 0.002 A˚
R factor = 0.031
wR factor = 0.080
data-to-parameter ratio = 13.6
topic single-crystal X-ray study
T = 123 K; mean (C–C) = 0.002 A˚
R factor = 0.031
wR factor = 0.080
data-to-parameter ratio = 13.6
description In the title compound, C12H15N3S, the mol­ecule deviates slightly from planarity, with a maximum deviation from the mean plane of the non-H atoms of 0.2756 (6) Å for the S atom and a torsion angle for the N-N-C-N fragment of -7.04 (16)°. In the crystal, mol­ecules are linked by N-H...S hydrogen-bond inter­actions, forming centrosymmetric dimers. Additionally, one weak intra­molecular N-H...N hydrogen-bond inter­action is observed. The crystal packing shows a herringbone arrangement viewed along the c axis.
publishDate 2014
dc.date.none.fl_str_mv 2014
2015-05-15T13:30:24Z
2015-05-15T13:30:24Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://scripts.iucr.org/cgi-bin/paper?S1600536814013889
Acta Crystallographica. Section E, v. 70, n. 7, p. o800, 2014.
1600-5368
http://hdl.handle.net/11449/123551
10.1107/s1600536814013889
ISSN1600-5368-2014-70-07-o800.pdf
7927677053650819
url http://scripts.iucr.org/cgi-bin/paper?S1600536814013889
http://hdl.handle.net/11449/123551
identifier_str_mv Acta Crystallographica. Section E, v. 70, n. 7, p. o800, 2014.
1600-5368
10.1107/s1600536814013889
ISSN1600-5368-2014-70-07-o800.pdf
7927677053650819
dc.language.iso.fl_str_mv por
language por
dc.relation.none.fl_str_mv Acta Crystallographica. Section E
0,138
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv o800
application/pdf
dc.source.none.fl_str_mv Currículo Lattes
reponame:Repositório Institucional da UNESP
instname:Universidade Estadual Paulista (UNESP)
instacron:UNESP
instname_str Universidade Estadual Paulista (UNESP)
instacron_str UNESP
institution UNESP
reponame_str Repositório Institucional da UNESP
collection Repositório Institucional da UNESP
repository.name.fl_str_mv Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)
repository.mail.fl_str_mv
_version_ 1808128776402370560

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