Revisiting ionic liquid structure‐property relationship: A critical analysis

Detalhes bibliográficos
Autor(a) principal: Silva, Wagner
Data de Publicação: 2020
Outros Autores: Zanatta, Marcileia, Ferreira, Ana Sofia, Corvo, Marta C., Cabrita, Eurico J.
Tipo de documento: Outros
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10362/114137
Resumo: grant number 201863/2014-6 UIDB/04378/2020 UIDB/50025/2020-2023 POCI-01-0145-FEDER-007688 PTDC/QUI-QFI/31508/2017 FCT-(ROTEIRO/0031/2013-PINFRA/22161/2016 UIDB/04378/2020
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oai_identifier_str oai:run.unl.pt:10362/114137
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network_name_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository_id_str 7160
spelling Revisiting ionic liquid structure‐property relationship: A critical analysisFree volumeIon pairIonic liquidPhysicochemical propertiesSupramolecular organizationTransport propertiesWaterCatalysisMolecular BiologySpectroscopyComputer Science ApplicationsPhysical and Theoretical ChemistryOrganic ChemistryInorganic Chemistrygrant number 201863/2014-6 UIDB/04378/2020 UIDB/50025/2020-2023 POCI-01-0145-FEDER-007688 PTDC/QUI-QFI/31508/2017 FCT-(ROTEIRO/0031/2013-PINFRA/22161/2016 UIDB/04378/2020In the last few years, ionic liquids (ILs) have been the focus of extensive studies concerning the relationship between structure and properties and how this impacts their application. Despite a large number of studies, several topics remain controversial or not fully answered, such as: the existence of ion pairs, the concept of free volume and the effect of water and its implications in the modulation of ILs physicochemical properties. In this paper, we present a critical review of state‐of-the‐art literature regarding structure–property relationship of ILs, we re‐examine analytical theories on the structure–property correlations and present new perspectives based on the existing data. The interrelation between transport properties (viscosity, diffusion, conductivity) of IL structure and free volume are analysed and discussed at a molecular level. In addition, we demonstrate how the analysis of microscopic features (particularly using NMR‐derived data) can be used to explain and predict macroscopic properties, reaching new perspectives on the properties and application of ILs.UCIBIO - Applied Molecular Biosciences UnitDQ - Departamento de QuímicaCENIMAT-i3N - Centro de Investigação de Materiais (Lab. Associado I3N)DCM - Departamento de Ciência dos MateriaisRUNSilva, WagnerZanatta, MarcileiaFerreira, Ana SofiaCorvo, Marta C.Cabrita, Eurico J.2021-03-19T23:27:34Z2020-10-192020-10-19T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/other37application/pdfhttp://hdl.handle.net/10362/114137eng1661-6596PURE: 26227474https://doi.org/10.3390/ijms21207745info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-05-22T17:51:16Zoai:run.unl.pt:10362/114137Portal AgregadorONGhttps://www.rcaap.pt/oai/openairemluisa.alvim@gmail.comopendoar:71602024-05-22T17:51:16Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Revisiting ionic liquid structure‐property relationship: A critical analysis
title Revisiting ionic liquid structure‐property relationship: A critical analysis
spellingShingle Revisiting ionic liquid structure‐property relationship: A critical analysis
Silva, Wagner
Free volume
Ion pair
Ionic liquid
Physicochemical properties
Supramolecular organization
Transport properties
Water
Catalysis
Molecular Biology
Spectroscopy
Computer Science Applications
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
title_short Revisiting ionic liquid structure‐property relationship: A critical analysis
title_full Revisiting ionic liquid structure‐property relationship: A critical analysis
title_fullStr Revisiting ionic liquid structure‐property relationship: A critical analysis
title_full_unstemmed Revisiting ionic liquid structure‐property relationship: A critical analysis
title_sort Revisiting ionic liquid structure‐property relationship: A critical analysis
author Silva, Wagner
author_facet Silva, Wagner
Zanatta, Marcileia
Ferreira, Ana Sofia
Corvo, Marta C.
Cabrita, Eurico J.
author_role author
author2 Zanatta, Marcileia
Ferreira, Ana Sofia
Corvo, Marta C.
Cabrita, Eurico J.
author2_role author
author
author
author
dc.contributor.none.fl_str_mv UCIBIO - Applied Molecular Biosciences Unit
DQ - Departamento de Química
CENIMAT-i3N - Centro de Investigação de Materiais (Lab. Associado I3N)
DCM - Departamento de Ciência dos Materiais
RUN
dc.contributor.author.fl_str_mv Silva, Wagner
Zanatta, Marcileia
Ferreira, Ana Sofia
Corvo, Marta C.
Cabrita, Eurico J.
dc.subject.por.fl_str_mv Free volume
Ion pair
Ionic liquid
Physicochemical properties
Supramolecular organization
Transport properties
Water
Catalysis
Molecular Biology
Spectroscopy
Computer Science Applications
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
topic Free volume
Ion pair
Ionic liquid
Physicochemical properties
Supramolecular organization
Transport properties
Water
Catalysis
Molecular Biology
Spectroscopy
Computer Science Applications
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
description grant number 201863/2014-6 UIDB/04378/2020 UIDB/50025/2020-2023 POCI-01-0145-FEDER-007688 PTDC/QUI-QFI/31508/2017 FCT-(ROTEIRO/0031/2013-PINFRA/22161/2016 UIDB/04378/2020
publishDate 2020
dc.date.none.fl_str_mv 2020-10-19
2020-10-19T00:00:00Z
2021-03-19T23:27:34Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/other
format other
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10362/114137
url http://hdl.handle.net/10362/114137
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 1661-6596
PURE: 26227474
https://doi.org/10.3390/ijms21207745
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 37
application/pdf
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv mluisa.alvim@gmail.com
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