Gold deposition from 1-butyl-1-methyl-pyrrolidinium dicyanamide ionic liquid at open-circuit and under potentiostatic control
Autor(a) principal: | |
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Data de Publicação: | 2013 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10400.9/1992 |
Resumo: | In this work, the deposition of gold on copper substrates from solutions of HAuCl4.3H2O in 1-butyl-1-methylpyrrolidinium dicyanamide was studied. Deposition was carried out in open-circuit and under potentiostatic control at temperatures from 293 to 353 K, in normal atmosphere, with deposition conditions allowing water from atmospheric absorption up to 0.8 wt.%. Films of gold were obtained by both methods. Deposition at open-circuit occurs by galvanic displacement mechanism. Involvement of Cu+ species in the electrodeposition process was suggested by cyclic voltammetry. Furthermore, copper incorporation in the gold films was confirmed by X-ray diffraction. SEM observation and XRD analysis show that films are nanocrystalline with a globular morphology except for the films formed under potentiostatic control at 353 K, which show a dendritic structure. The size of the crystallites determined by Scherrer's equation varies in the range from 6 to 25 nm. |
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Gold deposition from 1-butyl-1-methyl-pyrrolidinium dicyanamide ionic liquid at open-circuit and under potentiostatic controlGoldElectrodepositionIonic liquidsOpen-circuit depositionIn this work, the deposition of gold on copper substrates from solutions of HAuCl4.3H2O in 1-butyl-1-methylpyrrolidinium dicyanamide was studied. Deposition was carried out in open-circuit and under potentiostatic control at temperatures from 293 to 353 K, in normal atmosphere, with deposition conditions allowing water from atmospheric absorption up to 0.8 wt.%. Films of gold were obtained by both methods. Deposition at open-circuit occurs by galvanic displacement mechanism. Involvement of Cu+ species in the electrodeposition process was suggested by cyclic voltammetry. Furthermore, copper incorporation in the gold films was confirmed by X-ray diffraction. SEM observation and XRD analysis show that films are nanocrystalline with a globular morphology except for the films formed under potentiostatic control at 353 K, which show a dendritic structure. The size of the crystallites determined by Scherrer's equation varies in the range from 6 to 25 nm.ElsevierRepositório do LNEGSá, A.I. DeEugénio, S.Quaresma, S.Rangel, C. M.Vilar, R.2013-09-19T10:57:18Z2013-01-01T00:00:00Z2013-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10400.9/1992engSá, A.I. Correia de; Eugénio, S.; Quaresma, S.; Rangel, C.M.; Vilar, R. Gold deposition from 1-butyl-1-methyl-pyrrolidinium dicyanamide ionic liquid at open-circuit and under potentiostatic control. In: Surface and Coatings Technology, 2013, Vol. 232, p. 645-6510257-8972info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2022-09-06T12:26:43Zoai:repositorio.lneg.pt:10400.9/1992Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T15:34:51.021434Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Gold deposition from 1-butyl-1-methyl-pyrrolidinium dicyanamide ionic liquid at open-circuit and under potentiostatic control |
title |
Gold deposition from 1-butyl-1-methyl-pyrrolidinium dicyanamide ionic liquid at open-circuit and under potentiostatic control |
spellingShingle |
Gold deposition from 1-butyl-1-methyl-pyrrolidinium dicyanamide ionic liquid at open-circuit and under potentiostatic control Sá, A.I. De Gold Electrodeposition Ionic liquids Open-circuit deposition |
title_short |
Gold deposition from 1-butyl-1-methyl-pyrrolidinium dicyanamide ionic liquid at open-circuit and under potentiostatic control |
title_full |
Gold deposition from 1-butyl-1-methyl-pyrrolidinium dicyanamide ionic liquid at open-circuit and under potentiostatic control |
title_fullStr |
Gold deposition from 1-butyl-1-methyl-pyrrolidinium dicyanamide ionic liquid at open-circuit and under potentiostatic control |
title_full_unstemmed |
Gold deposition from 1-butyl-1-methyl-pyrrolidinium dicyanamide ionic liquid at open-circuit and under potentiostatic control |
title_sort |
Gold deposition from 1-butyl-1-methyl-pyrrolidinium dicyanamide ionic liquid at open-circuit and under potentiostatic control |
author |
Sá, A.I. De |
author_facet |
Sá, A.I. De Eugénio, S. Quaresma, S. Rangel, C. M. Vilar, R. |
author_role |
author |
author2 |
Eugénio, S. Quaresma, S. Rangel, C. M. Vilar, R. |
author2_role |
author author author author |
dc.contributor.none.fl_str_mv |
Repositório do LNEG |
dc.contributor.author.fl_str_mv |
Sá, A.I. De Eugénio, S. Quaresma, S. Rangel, C. M. Vilar, R. |
dc.subject.por.fl_str_mv |
Gold Electrodeposition Ionic liquids Open-circuit deposition |
topic |
Gold Electrodeposition Ionic liquids Open-circuit deposition |
description |
In this work, the deposition of gold on copper substrates from solutions of HAuCl4.3H2O in 1-butyl-1-methylpyrrolidinium dicyanamide was studied. Deposition was carried out in open-circuit and under potentiostatic control at temperatures from 293 to 353 K, in normal atmosphere, with deposition conditions allowing water from atmospheric absorption up to 0.8 wt.%. Films of gold were obtained by both methods. Deposition at open-circuit occurs by galvanic displacement mechanism. Involvement of Cu+ species in the electrodeposition process was suggested by cyclic voltammetry. Furthermore, copper incorporation in the gold films was confirmed by X-ray diffraction. SEM observation and XRD analysis show that films are nanocrystalline with a globular morphology except for the films formed under potentiostatic control at 353 K, which show a dendritic structure. The size of the crystallites determined by Scherrer's equation varies in the range from 6 to 25 nm. |
publishDate |
2013 |
dc.date.none.fl_str_mv |
2013-09-19T10:57:18Z 2013-01-01T00:00:00Z 2013-01-01T00:00:00Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10400.9/1992 |
url |
http://hdl.handle.net/10400.9/1992 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Sá, A.I. Correia de; Eugénio, S.; Quaresma, S.; Rangel, C.M.; Vilar, R. Gold deposition from 1-butyl-1-methyl-pyrrolidinium dicyanamide ionic liquid at open-circuit and under potentiostatic control. In: Surface and Coatings Technology, 2013, Vol. 232, p. 645-651 0257-8972 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
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Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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RCAAP |
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RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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1799130212956372992 |