Gold deposition from 1-butyl-1-methyl-pyrrolidinium dicyanamide ionic liquid at open-circuit and under potentiostatic control

Detalhes bibliográficos
Autor(a) principal: Sá, A.I. De
Data de Publicação: 2013
Outros Autores: Eugénio, S., Quaresma, S., Rangel, C. M., Vilar, R.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10400.9/1992
Resumo: In this work, the deposition of gold on copper substrates from solutions of HAuCl4.3H2O in 1-butyl-1-methylpyrrolidinium dicyanamide was studied. Deposition was carried out in open-circuit and under potentiostatic control at temperatures from 293 to 353 K, in normal atmosphere, with deposition conditions allowing water from atmospheric absorption up to 0.8 wt.%. Films of gold were obtained by both methods. Deposition at open-circuit occurs by galvanic displacement mechanism. Involvement of Cu+ species in the electrodeposition process was suggested by cyclic voltammetry. Furthermore, copper incorporation in the gold films was confirmed by X-ray diffraction. SEM observation and XRD analysis show that films are nanocrystalline with a globular morphology except for the films formed under potentiostatic control at 353 K, which show a dendritic structure. The size of the crystallites determined by Scherrer's equation varies in the range from 6 to 25 nm.
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spelling Gold deposition from 1-butyl-1-methyl-pyrrolidinium dicyanamide ionic liquid at open-circuit and under potentiostatic controlGoldElectrodepositionIonic liquidsOpen-circuit depositionIn this work, the deposition of gold on copper substrates from solutions of HAuCl4.3H2O in 1-butyl-1-methylpyrrolidinium dicyanamide was studied. Deposition was carried out in open-circuit and under potentiostatic control at temperatures from 293 to 353 K, in normal atmosphere, with deposition conditions allowing water from atmospheric absorption up to 0.8 wt.%. Films of gold were obtained by both methods. Deposition at open-circuit occurs by galvanic displacement mechanism. Involvement of Cu+ species in the electrodeposition process was suggested by cyclic voltammetry. Furthermore, copper incorporation in the gold films was confirmed by X-ray diffraction. SEM observation and XRD analysis show that films are nanocrystalline with a globular morphology except for the films formed under potentiostatic control at 353 K, which show a dendritic structure. The size of the crystallites determined by Scherrer's equation varies in the range from 6 to 25 nm.ElsevierRepositório do LNEGSá, A.I. DeEugénio, S.Quaresma, S.Rangel, C. M.Vilar, R.2013-09-19T10:57:18Z2013-01-01T00:00:00Z2013-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10400.9/1992engSá, A.I. Correia de; Eugénio, S.; Quaresma, S.; Rangel, C.M.; Vilar, R. Gold deposition from 1-butyl-1-methyl-pyrrolidinium dicyanamide ionic liquid at open-circuit and under potentiostatic control. In: Surface and Coatings Technology, 2013, Vol. 232, p. 645-6510257-8972info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2022-09-06T12:26:43Zoai:repositorio.lneg.pt:10400.9/1992Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T15:34:51.021434Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Gold deposition from 1-butyl-1-methyl-pyrrolidinium dicyanamide ionic liquid at open-circuit and under potentiostatic control
title Gold deposition from 1-butyl-1-methyl-pyrrolidinium dicyanamide ionic liquid at open-circuit and under potentiostatic control
spellingShingle Gold deposition from 1-butyl-1-methyl-pyrrolidinium dicyanamide ionic liquid at open-circuit and under potentiostatic control
Sá, A.I. De
Gold
Electrodeposition
Ionic liquids
Open-circuit deposition
title_short Gold deposition from 1-butyl-1-methyl-pyrrolidinium dicyanamide ionic liquid at open-circuit and under potentiostatic control
title_full Gold deposition from 1-butyl-1-methyl-pyrrolidinium dicyanamide ionic liquid at open-circuit and under potentiostatic control
title_fullStr Gold deposition from 1-butyl-1-methyl-pyrrolidinium dicyanamide ionic liquid at open-circuit and under potentiostatic control
title_full_unstemmed Gold deposition from 1-butyl-1-methyl-pyrrolidinium dicyanamide ionic liquid at open-circuit and under potentiostatic control
title_sort Gold deposition from 1-butyl-1-methyl-pyrrolidinium dicyanamide ionic liquid at open-circuit and under potentiostatic control
author Sá, A.I. De
author_facet Sá, A.I. De
Eugénio, S.
Quaresma, S.
Rangel, C. M.
Vilar, R.
author_role author
author2 Eugénio, S.
Quaresma, S.
Rangel, C. M.
Vilar, R.
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Repositório do LNEG
dc.contributor.author.fl_str_mv Sá, A.I. De
Eugénio, S.
Quaresma, S.
Rangel, C. M.
Vilar, R.
dc.subject.por.fl_str_mv Gold
Electrodeposition
Ionic liquids
Open-circuit deposition
topic Gold
Electrodeposition
Ionic liquids
Open-circuit deposition
description In this work, the deposition of gold on copper substrates from solutions of HAuCl4.3H2O in 1-butyl-1-methylpyrrolidinium dicyanamide was studied. Deposition was carried out in open-circuit and under potentiostatic control at temperatures from 293 to 353 K, in normal atmosphere, with deposition conditions allowing water from atmospheric absorption up to 0.8 wt.%. Films of gold were obtained by both methods. Deposition at open-circuit occurs by galvanic displacement mechanism. Involvement of Cu+ species in the electrodeposition process was suggested by cyclic voltammetry. Furthermore, copper incorporation in the gold films was confirmed by X-ray diffraction. SEM observation and XRD analysis show that films are nanocrystalline with a globular morphology except for the films formed under potentiostatic control at 353 K, which show a dendritic structure. The size of the crystallites determined by Scherrer's equation varies in the range from 6 to 25 nm.
publishDate 2013
dc.date.none.fl_str_mv 2013-09-19T10:57:18Z
2013-01-01T00:00:00Z
2013-01-01T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10400.9/1992
url http://hdl.handle.net/10400.9/1992
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Sá, A.I. Correia de; Eugénio, S.; Quaresma, S.; Rangel, C.M.; Vilar, R. Gold deposition from 1-butyl-1-methyl-pyrrolidinium dicyanamide ionic liquid at open-circuit and under potentiostatic control. In: Surface and Coatings Technology, 2013, Vol. 232, p. 645-651
0257-8972
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
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repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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