Indigo revisited
Autor(a) principal: | |
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Data de Publicação: | 2003 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/1822/1821 |
Resumo: | The synthesis of indigo and five derivatives containing electron-donating groups (methyl or methoxyl) by known methods, is described. The Baeyer-Drewsen method was followed in most cases. Another product containing ester groups was prepared via the corresponding 3-formylindole by a Dakin reaction. The blue dyes were characterized by their absorption (UV-Vis and IR) and NMR spectra, and elemental analysis or mass spectrometry. The objective of this study was to prepare and fully characterize indigo derivatives with electron-donating groups and to obtain and characterize a carboxylated indigo derivative. |
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Indigo revisitedDyes,DimethylindigoTetramethoxyindigoBaeyer-Drewsen methodThe synthesis of indigo and five derivatives containing electron-donating groups (methyl or methoxyl) by known methods, is described. The Baeyer-Drewsen method was followed in most cases. Another product containing ester groups was prepared via the corresponding 3-formylindole by a Dakin reaction. The blue dyes were characterized by their absorption (UV-Vis and IR) and NMR spectra, and elemental analysis or mass spectrometry. The objective of this study was to prepare and fully characterize indigo derivatives with electron-donating groups and to obtain and characterize a carboxylated indigo derivative.Fundação para a Ciência e Tecnologia - PRAXIS XXI2/2.1/QUI/44/94. FEDER. Departamento de Gestão de Recursos Educativos do Ministério da Educação - MIGMGT.University of Leeds. Department of Colour ChemistryUniversidade do MinhoTravasso, Maria Irene G. M. G.Santos, Paula C. S.Campos, Ana M. F. OliveiraRaposo, M. Manuela M.Prasitpan, N.20032003-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/1822/1821eng"Advances in colour science and technology". 6:4 (2003) 95-99.info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-07-21T12:53:28Zoai:repositorium.sdum.uminho.pt:1822/1821Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T19:52:51.527376Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Indigo revisited |
title |
Indigo revisited |
spellingShingle |
Indigo revisited Travasso, Maria Irene G. M. G. Dyes, Dimethylindigo Tetramethoxyindigo Baeyer-Drewsen method |
title_short |
Indigo revisited |
title_full |
Indigo revisited |
title_fullStr |
Indigo revisited |
title_full_unstemmed |
Indigo revisited |
title_sort |
Indigo revisited |
author |
Travasso, Maria Irene G. M. G. |
author_facet |
Travasso, Maria Irene G. M. G. Santos, Paula C. S. Campos, Ana M. F. Oliveira Raposo, M. Manuela M. Prasitpan, N. |
author_role |
author |
author2 |
Santos, Paula C. S. Campos, Ana M. F. Oliveira Raposo, M. Manuela M. Prasitpan, N. |
author2_role |
author author author author |
dc.contributor.none.fl_str_mv |
Universidade do Minho |
dc.contributor.author.fl_str_mv |
Travasso, Maria Irene G. M. G. Santos, Paula C. S. Campos, Ana M. F. Oliveira Raposo, M. Manuela M. Prasitpan, N. |
dc.subject.por.fl_str_mv |
Dyes, Dimethylindigo Tetramethoxyindigo Baeyer-Drewsen method |
topic |
Dyes, Dimethylindigo Tetramethoxyindigo Baeyer-Drewsen method |
description |
The synthesis of indigo and five derivatives containing electron-donating groups (methyl or methoxyl) by known methods, is described. The Baeyer-Drewsen method was followed in most cases. Another product containing ester groups was prepared via the corresponding 3-formylindole by a Dakin reaction. The blue dyes were characterized by their absorption (UV-Vis and IR) and NMR spectra, and elemental analysis or mass spectrometry. The objective of this study was to prepare and fully characterize indigo derivatives with electron-donating groups and to obtain and characterize a carboxylated indigo derivative. |
publishDate |
2003 |
dc.date.none.fl_str_mv |
2003 2003-01-01T00:00:00Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/1822/1821 |
url |
http://hdl.handle.net/1822/1821 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
"Advances in colour science and technology". 6:4 (2003) 95-99. |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
University of Leeds. Department of Colour Chemistry |
publisher.none.fl_str_mv |
University of Leeds. Department of Colour Chemistry |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
repository.mail.fl_str_mv |
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1799133122528280576 |