Electroepoxidation of natural and synthetic alkenes mediated by sodium bromide

Detalhes bibliográficos
Autor(a) principal: Massuquinini, Inês
Data de Publicação: 2009
Outros Autores: Mendonça, António J., Esteves, Ana Paula, Mendonça, Dina I., Medeiros, Maria José
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/1822/25656
Resumo: Electroepoxidation of synthetic alkenes (styrene, trans-stilbene and trans-b-methylstyrene) and of some natural terpenes (limonene, terpinolene, geraniol, a-terpinene, g-terpinene and a-terpineol) mediated by sodium bromide was performed in MeCN:H2O (4:1) at platinum electrodes. The indirect electrochemical oxidation of the olefins led to the corresponding epoxides in yields ranging from 23% to 79%.
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spelling Electroepoxidation of natural and synthetic alkenes mediated by sodium bromideElectrochemical epoxidationSodium bromideAlkenesTerpenesEpoxydation électrochimieBromure de sodiumAlcènesTerpènesScience & TechnologyElectroepoxidation of synthetic alkenes (styrene, trans-stilbene and trans-b-methylstyrene) and of some natural terpenes (limonene, terpinolene, geraniol, a-terpinene, g-terpinene and a-terpineol) mediated by sodium bromide was performed in MeCN:H2O (4:1) at platinum electrodes. The indirect electrochemical oxidation of the olefins led to the corresponding epoxides in yields ranging from 23% to 79%.L’électroépoxydation d’alcènes synthétiques (styrène, trans-stilbène et trans-β- méthylstyrène) et d’alcènes naturels terpéniques (limonène, terpinolène, géraniol, α-terpinène, γ-terpinène et α-terpinéol) à l’aide de bromure de sodium a été réalisée dans un mélange MeCN:H2O (4:1) avec des électrodes de platine. L’oxydation électrochimique indirecte d’oléfines conduit aux époxydes correspondants avec des rendements allant de 23% à 79%.Fundação para a Ciência e a Tecnologia (FCT)Elsevier MassonUniversidade do MinhoMassuquinini, InêsMendonça, António J.Esteves, Ana PaulaMendonça, Dina I.Medeiros, Maria José2009-012009-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/1822/25656eng1631-074810.1016/j.crci.2008.10.014info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-07-21T12:30:44Zoai:repositorium.sdum.uminho.pt:1822/25656Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T19:25:58.824449Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Electroepoxidation of natural and synthetic alkenes mediated by sodium bromide
title Electroepoxidation of natural and synthetic alkenes mediated by sodium bromide
spellingShingle Electroepoxidation of natural and synthetic alkenes mediated by sodium bromide
Massuquinini, Inês
Electrochemical epoxidation
Sodium bromide
Alkenes
Terpenes
Epoxydation électrochimie
Bromure de sodium
Alcènes
Terpènes
Science & Technology
title_short Electroepoxidation of natural and synthetic alkenes mediated by sodium bromide
title_full Electroepoxidation of natural and synthetic alkenes mediated by sodium bromide
title_fullStr Electroepoxidation of natural and synthetic alkenes mediated by sodium bromide
title_full_unstemmed Electroepoxidation of natural and synthetic alkenes mediated by sodium bromide
title_sort Electroepoxidation of natural and synthetic alkenes mediated by sodium bromide
author Massuquinini, Inês
author_facet Massuquinini, Inês
Mendonça, António J.
Esteves, Ana Paula
Mendonça, Dina I.
Medeiros, Maria José
author_role author
author2 Mendonça, António J.
Esteves, Ana Paula
Mendonça, Dina I.
Medeiros, Maria José
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Universidade do Minho
dc.contributor.author.fl_str_mv Massuquinini, Inês
Mendonça, António J.
Esteves, Ana Paula
Mendonça, Dina I.
Medeiros, Maria José
dc.subject.por.fl_str_mv Electrochemical epoxidation
Sodium bromide
Alkenes
Terpenes
Epoxydation électrochimie
Bromure de sodium
Alcènes
Terpènes
Science & Technology
topic Electrochemical epoxidation
Sodium bromide
Alkenes
Terpenes
Epoxydation électrochimie
Bromure de sodium
Alcènes
Terpènes
Science & Technology
description Electroepoxidation of synthetic alkenes (styrene, trans-stilbene and trans-b-methylstyrene) and of some natural terpenes (limonene, terpinolene, geraniol, a-terpinene, g-terpinene and a-terpineol) mediated by sodium bromide was performed in MeCN:H2O (4:1) at platinum electrodes. The indirect electrochemical oxidation of the olefins led to the corresponding epoxides in yields ranging from 23% to 79%.
publishDate 2009
dc.date.none.fl_str_mv 2009-01
2009-01-01T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/1822/25656
url http://hdl.handle.net/1822/25656
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 1631-0748
10.1016/j.crci.2008.10.014
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier Masson
publisher.none.fl_str_mv Elsevier Masson
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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