Feasibility of Use of the Microwave Induced Plasma Atomic Emission Detector as a Compound Independent Detector for Quantitative Chromatographic Analysis

Detalhes bibliográficos
Autor(a) principal: Augusto,Fabio
Data de Publicação: 1998
Outros Autores: Rocha,Eduardo Carasek da, Montero,Larisse, Valente,Antonio Luiz Pires
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531998000100004
Resumo: The independence of the response of a Microwave Induced Plasma Atomic Emission Detector (GC-MIP) for Gas Chromatography with the chemical structure of the analyte has been exploited using as teste samples nine organochlorine compounds. With signal monitoring at the chlorine 479.5 nm emission line and after proper adjustment of the operational conditions of the GC-MIP the agreement of the detector response for the nine compounds was of 8.5% or less, which is adequate for the use of the compound-independent calibration method. It is proposed that the reliability of the quantitation after applying the compound-independent calibration methodology may be enhanced if a set of calibration compounds is used instead of a single calibration compound.
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spelling Feasibility of Use of the Microwave Induced Plasma Atomic Emission Detector as a Compound Independent Detector for Quantitative Chromatographic Analysismicrowave induced plasmachlorine specific detectioncompound-independent calibration methodThe independence of the response of a Microwave Induced Plasma Atomic Emission Detector (GC-MIP) for Gas Chromatography with the chemical structure of the analyte has been exploited using as teste samples nine organochlorine compounds. With signal monitoring at the chlorine 479.5 nm emission line and after proper adjustment of the operational conditions of the GC-MIP the agreement of the detector response for the nine compounds was of 8.5% or less, which is adequate for the use of the compound-independent calibration method. It is proposed that the reliability of the quantitation after applying the compound-independent calibration methodology may be enhanced if a set of calibration compounds is used instead of a single calibration compound.Sociedade Brasileira de Química1998-02-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531998000100004Journal of the Brazilian Chemical Society v.9 n.1 1998reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50531998000100004info:eu-repo/semantics/openAccessAugusto,FabioRocha,Eduardo Carasek daMontero,LarisseValente,Antonio Luiz Pireseng2008-03-17T00:00:00Zoai:scielo:S0103-50531998000100004Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2008-03-17T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Feasibility of Use of the Microwave Induced Plasma Atomic Emission Detector as a Compound Independent Detector for Quantitative Chromatographic Analysis
title Feasibility of Use of the Microwave Induced Plasma Atomic Emission Detector as a Compound Independent Detector for Quantitative Chromatographic Analysis
spellingShingle Feasibility of Use of the Microwave Induced Plasma Atomic Emission Detector as a Compound Independent Detector for Quantitative Chromatographic Analysis
Augusto,Fabio
microwave induced plasma
chlorine specific detection
compound-independent calibration method
title_short Feasibility of Use of the Microwave Induced Plasma Atomic Emission Detector as a Compound Independent Detector for Quantitative Chromatographic Analysis
title_full Feasibility of Use of the Microwave Induced Plasma Atomic Emission Detector as a Compound Independent Detector for Quantitative Chromatographic Analysis
title_fullStr Feasibility of Use of the Microwave Induced Plasma Atomic Emission Detector as a Compound Independent Detector for Quantitative Chromatographic Analysis
title_full_unstemmed Feasibility of Use of the Microwave Induced Plasma Atomic Emission Detector as a Compound Independent Detector for Quantitative Chromatographic Analysis
title_sort Feasibility of Use of the Microwave Induced Plasma Atomic Emission Detector as a Compound Independent Detector for Quantitative Chromatographic Analysis
author Augusto,Fabio
author_facet Augusto,Fabio
Rocha,Eduardo Carasek da
Montero,Larisse
Valente,Antonio Luiz Pires
author_role author
author2 Rocha,Eduardo Carasek da
Montero,Larisse
Valente,Antonio Luiz Pires
author2_role author
author
author
dc.contributor.author.fl_str_mv Augusto,Fabio
Rocha,Eduardo Carasek da
Montero,Larisse
Valente,Antonio Luiz Pires
dc.subject.por.fl_str_mv microwave induced plasma
chlorine specific detection
compound-independent calibration method
topic microwave induced plasma
chlorine specific detection
compound-independent calibration method
description The independence of the response of a Microwave Induced Plasma Atomic Emission Detector (GC-MIP) for Gas Chromatography with the chemical structure of the analyte has been exploited using as teste samples nine organochlorine compounds. With signal monitoring at the chlorine 479.5 nm emission line and after proper adjustment of the operational conditions of the GC-MIP the agreement of the detector response for the nine compounds was of 8.5% or less, which is adequate for the use of the compound-independent calibration method. It is proposed that the reliability of the quantitation after applying the compound-independent calibration methodology may be enhanced if a set of calibration compounds is used instead of a single calibration compound.
publishDate 1998
dc.date.none.fl_str_mv 1998-02-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531998000100004
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531998000100004
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0103-50531998000100004
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.9 n.1 1998
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
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