Feasibility of Use of the Microwave Induced Plasma Atomic Emission Detector as a Compound Independent Detector for Quantitative Chromatographic Analysis
Autor(a) principal: | |
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Data de Publicação: | 1998 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Journal of the Brazilian Chemical Society (Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531998000100004 |
Resumo: | The independence of the response of a Microwave Induced Plasma Atomic Emission Detector (GC-MIP) for Gas Chromatography with the chemical structure of the analyte has been exploited using as teste samples nine organochlorine compounds. With signal monitoring at the chlorine 479.5 nm emission line and after proper adjustment of the operational conditions of the GC-MIP the agreement of the detector response for the nine compounds was of 8.5% or less, which is adequate for the use of the compound-independent calibration method. It is proposed that the reliability of the quantitation after applying the compound-independent calibration methodology may be enhanced if a set of calibration compounds is used instead of a single calibration compound. |
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Journal of the Brazilian Chemical Society (Online) |
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Feasibility of Use of the Microwave Induced Plasma Atomic Emission Detector as a Compound Independent Detector for Quantitative Chromatographic Analysismicrowave induced plasmachlorine specific detectioncompound-independent calibration methodThe independence of the response of a Microwave Induced Plasma Atomic Emission Detector (GC-MIP) for Gas Chromatography with the chemical structure of the analyte has been exploited using as teste samples nine organochlorine compounds. With signal monitoring at the chlorine 479.5 nm emission line and after proper adjustment of the operational conditions of the GC-MIP the agreement of the detector response for the nine compounds was of 8.5% or less, which is adequate for the use of the compound-independent calibration method. It is proposed that the reliability of the quantitation after applying the compound-independent calibration methodology may be enhanced if a set of calibration compounds is used instead of a single calibration compound.Sociedade Brasileira de Química1998-02-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531998000100004Journal of the Brazilian Chemical Society v.9 n.1 1998reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50531998000100004info:eu-repo/semantics/openAccessAugusto,FabioRocha,Eduardo Carasek daMontero,LarisseValente,Antonio Luiz Pireseng2008-03-17T00:00:00Zoai:scielo:S0103-50531998000100004Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2008-03-17T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false |
dc.title.none.fl_str_mv |
Feasibility of Use of the Microwave Induced Plasma Atomic Emission Detector as a Compound Independent Detector for Quantitative Chromatographic Analysis |
title |
Feasibility of Use of the Microwave Induced Plasma Atomic Emission Detector as a Compound Independent Detector for Quantitative Chromatographic Analysis |
spellingShingle |
Feasibility of Use of the Microwave Induced Plasma Atomic Emission Detector as a Compound Independent Detector for Quantitative Chromatographic Analysis Augusto,Fabio microwave induced plasma chlorine specific detection compound-independent calibration method |
title_short |
Feasibility of Use of the Microwave Induced Plasma Atomic Emission Detector as a Compound Independent Detector for Quantitative Chromatographic Analysis |
title_full |
Feasibility of Use of the Microwave Induced Plasma Atomic Emission Detector as a Compound Independent Detector for Quantitative Chromatographic Analysis |
title_fullStr |
Feasibility of Use of the Microwave Induced Plasma Atomic Emission Detector as a Compound Independent Detector for Quantitative Chromatographic Analysis |
title_full_unstemmed |
Feasibility of Use of the Microwave Induced Plasma Atomic Emission Detector as a Compound Independent Detector for Quantitative Chromatographic Analysis |
title_sort |
Feasibility of Use of the Microwave Induced Plasma Atomic Emission Detector as a Compound Independent Detector for Quantitative Chromatographic Analysis |
author |
Augusto,Fabio |
author_facet |
Augusto,Fabio Rocha,Eduardo Carasek da Montero,Larisse Valente,Antonio Luiz Pires |
author_role |
author |
author2 |
Rocha,Eduardo Carasek da Montero,Larisse Valente,Antonio Luiz Pires |
author2_role |
author author author |
dc.contributor.author.fl_str_mv |
Augusto,Fabio Rocha,Eduardo Carasek da Montero,Larisse Valente,Antonio Luiz Pires |
dc.subject.por.fl_str_mv |
microwave induced plasma chlorine specific detection compound-independent calibration method |
topic |
microwave induced plasma chlorine specific detection compound-independent calibration method |
description |
The independence of the response of a Microwave Induced Plasma Atomic Emission Detector (GC-MIP) for Gas Chromatography with the chemical structure of the analyte has been exploited using as teste samples nine organochlorine compounds. With signal monitoring at the chlorine 479.5 nm emission line and after proper adjustment of the operational conditions of the GC-MIP the agreement of the detector response for the nine compounds was of 8.5% or less, which is adequate for the use of the compound-independent calibration method. It is proposed that the reliability of the quantitation after applying the compound-independent calibration methodology may be enhanced if a set of calibration compounds is used instead of a single calibration compound. |
publishDate |
1998 |
dc.date.none.fl_str_mv |
1998-02-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531998000100004 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531998000100004 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/S0103-50531998000100004 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
dc.source.none.fl_str_mv |
Journal of the Brazilian Chemical Society v.9 n.1 1998 reponame:Journal of the Brazilian Chemical Society (Online) instname:Sociedade Brasileira de Química (SBQ) instacron:SBQ |
instname_str |
Sociedade Brasileira de Química (SBQ) |
instacron_str |
SBQ |
institution |
SBQ |
reponame_str |
Journal of the Brazilian Chemical Society (Online) |
collection |
Journal of the Brazilian Chemical Society (Online) |
repository.name.fl_str_mv |
Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ) |
repository.mail.fl_str_mv |
||office@jbcs.sbq.org.br |
_version_ |
1750318163358121984 |