Allylic chlorination of terpenic olefins using a combination of MoCl5 and NaOCl

Detalhes bibliográficos
Autor(a) principal: Boualy,Brahim
Data de Publicação: 2011
Outros Autores: Firdoussi,Larbi El, Ali,Mustapha Ait, Karim,Abdellah
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532011000700010
Resumo: MoCl5 is applied as efficient agent in allylic chlorination of terpenic olefins in the presence of NaOCl as chlorine donor. Various terpenes are converted to the corresponding allylic chlorides in moderate to good yield under mild and optimized reaction conditions. Different molybdenum precursors are also studied. Among them, MoO3 gives good yield, but after a longer reaction time.
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spelling Allylic chlorination of terpenic olefins using a combination of MoCl5 and NaOClmonoterpenesallylic chlorinationmolybdenumsodium hypochloriteMoCl5 is applied as efficient agent in allylic chlorination of terpenic olefins in the presence of NaOCl as chlorine donor. Various terpenes are converted to the corresponding allylic chlorides in moderate to good yield under mild and optimized reaction conditions. Different molybdenum precursors are also studied. Among them, MoO3 gives good yield, but after a longer reaction time.Sociedade Brasileira de Química2011-07-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532011000700010Journal of the Brazilian Chemical Society v.22 n.7 2011reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50532011000700010info:eu-repo/semantics/openAccessBoualy,BrahimFirdoussi,Larbi ElAli,Mustapha AitKarim,Abdellaheng2011-07-22T00:00:00Zoai:scielo:S0103-50532011000700010Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2011-07-22T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Allylic chlorination of terpenic olefins using a combination of MoCl5 and NaOCl
title Allylic chlorination of terpenic olefins using a combination of MoCl5 and NaOCl
spellingShingle Allylic chlorination of terpenic olefins using a combination of MoCl5 and NaOCl
Boualy,Brahim
monoterpenes
allylic chlorination
molybdenum
sodium hypochlorite
title_short Allylic chlorination of terpenic olefins using a combination of MoCl5 and NaOCl
title_full Allylic chlorination of terpenic olefins using a combination of MoCl5 and NaOCl
title_fullStr Allylic chlorination of terpenic olefins using a combination of MoCl5 and NaOCl
title_full_unstemmed Allylic chlorination of terpenic olefins using a combination of MoCl5 and NaOCl
title_sort Allylic chlorination of terpenic olefins using a combination of MoCl5 and NaOCl
author Boualy,Brahim
author_facet Boualy,Brahim
Firdoussi,Larbi El
Ali,Mustapha Ait
Karim,Abdellah
author_role author
author2 Firdoussi,Larbi El
Ali,Mustapha Ait
Karim,Abdellah
author2_role author
author
author
dc.contributor.author.fl_str_mv Boualy,Brahim
Firdoussi,Larbi El
Ali,Mustapha Ait
Karim,Abdellah
dc.subject.por.fl_str_mv monoterpenes
allylic chlorination
molybdenum
sodium hypochlorite
topic monoterpenes
allylic chlorination
molybdenum
sodium hypochlorite
description MoCl5 is applied as efficient agent in allylic chlorination of terpenic olefins in the presence of NaOCl as chlorine donor. Various terpenes are converted to the corresponding allylic chlorides in moderate to good yield under mild and optimized reaction conditions. Different molybdenum precursors are also studied. Among them, MoO3 gives good yield, but after a longer reaction time.
publishDate 2011
dc.date.none.fl_str_mv 2011-07-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532011000700010
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532011000700010
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0103-50532011000700010
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.22 n.7 2011
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
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