InCl3/NaClO: a reagent for allylic chlorination of terminal olefins

Detalhes bibliográficos
Autor(a) principal: Pisoni,Diego S.
Data de Publicação: 2006
Outros Autores: Gamba,Douglas, Fonseca,Carlos V., Costa,Jessie S. da, Petzhold,Cesar L., Oliveira,Eduardo R. de, Ceschi,Marco A.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532006000200015
Resumo: Indium trichloride promotes the chlorination of terminal olefins in the presence of sodium hypochlorite with good results. Carvone was chosen as a model compound to examine some of the general features of this reaction, such as stoichiometry, temperature, reaction time and product conversion. Treatment of beta-pinene with sodium hypochlorite in the presence of indium trichloride resulted in a facile rearrangement to selectively yield perillyl chloride, which is an important precursor for C-7 oxygenated limonenes.
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spelling InCl3/NaClO: a reagent for allylic chlorination of terminal olefinsallylic chlorinationindium trichloridesodium hypochoriteIndium trichloride promotes the chlorination of terminal olefins in the presence of sodium hypochlorite with good results. Carvone was chosen as a model compound to examine some of the general features of this reaction, such as stoichiometry, temperature, reaction time and product conversion. Treatment of beta-pinene with sodium hypochlorite in the presence of indium trichloride resulted in a facile rearrangement to selectively yield perillyl chloride, which is an important precursor for C-7 oxygenated limonenes.Sociedade Brasileira de Química2006-04-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532006000200015Journal of the Brazilian Chemical Society v.17 n.2 2006reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50532006000200015info:eu-repo/semantics/openAccessPisoni,Diego S.Gamba,DouglasFonseca,Carlos V.Costa,Jessie S. daPetzhold,Cesar L.Oliveira,Eduardo R. deCeschi,Marco A.eng2017-05-05T00:00:00Zoai:scielo:S0103-50532006000200015Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2017-05-05T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv InCl3/NaClO: a reagent for allylic chlorination of terminal olefins
title InCl3/NaClO: a reagent for allylic chlorination of terminal olefins
spellingShingle InCl3/NaClO: a reagent for allylic chlorination of terminal olefins
Pisoni,Diego S.
allylic chlorination
indium trichloride
sodium hypochorite
title_short InCl3/NaClO: a reagent for allylic chlorination of terminal olefins
title_full InCl3/NaClO: a reagent for allylic chlorination of terminal olefins
title_fullStr InCl3/NaClO: a reagent for allylic chlorination of terminal olefins
title_full_unstemmed InCl3/NaClO: a reagent for allylic chlorination of terminal olefins
title_sort InCl3/NaClO: a reagent for allylic chlorination of terminal olefins
author Pisoni,Diego S.
author_facet Pisoni,Diego S.
Gamba,Douglas
Fonseca,Carlos V.
Costa,Jessie S. da
Petzhold,Cesar L.
Oliveira,Eduardo R. de
Ceschi,Marco A.
author_role author
author2 Gamba,Douglas
Fonseca,Carlos V.
Costa,Jessie S. da
Petzhold,Cesar L.
Oliveira,Eduardo R. de
Ceschi,Marco A.
author2_role author
author
author
author
author
author
dc.contributor.author.fl_str_mv Pisoni,Diego S.
Gamba,Douglas
Fonseca,Carlos V.
Costa,Jessie S. da
Petzhold,Cesar L.
Oliveira,Eduardo R. de
Ceschi,Marco A.
dc.subject.por.fl_str_mv allylic chlorination
indium trichloride
sodium hypochorite
topic allylic chlorination
indium trichloride
sodium hypochorite
description Indium trichloride promotes the chlorination of terminal olefins in the presence of sodium hypochlorite with good results. Carvone was chosen as a model compound to examine some of the general features of this reaction, such as stoichiometry, temperature, reaction time and product conversion. Treatment of beta-pinene with sodium hypochlorite in the presence of indium trichloride resulted in a facile rearrangement to selectively yield perillyl chloride, which is an important precursor for C-7 oxygenated limonenes.
publishDate 2006
dc.date.none.fl_str_mv 2006-04-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532006000200015
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532006000200015
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0103-50532006000200015
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.17 n.2 2006
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
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