Study of growth, optical and morphological properties of Zn(O;OH)S thin films synthesized by CBD method

• Autor(a) principal: Vallejo,W.
• Data de Publicação: 2011
• Outros Autores: Romero,E., Gordillo,G.
• Tipo de documento: Artigo
• Idioma: eng
• Título da fonte: Journal of the Brazilian Chemical Society (Online)
• Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532011001200008
• topic: solar cells; buffer layer; Zn(O,OH)S; CBD

In this work, we investigated thin films of Zn(O;OH)S as substitute of thin films of CdS, which are conventionally used as buffer layer in chalcopyrite based solar cells. Thin films of Zn(O;OH)S were deposited by chemical bath deposition (CBD) method using a chemical bath containing thiourea, zinc acetate, sodium citrate and ammonium. Soda-lime glass and soda-lime glass covered with thin films of CuGaSe2 (CGS) were used as substrates in the deposition of thin films of Zn(O;OH)S. The Avrami equation was used to study the growth rate of thin film of Zn(O,OH)S on both substrates. The influence of the substrate kind and time of synthesis on the growth rate, optical and morphological properties of the as-grown thin films of Zn(O,OH)S have been carried out through spectrophotometry and atomic force microscopy (AFM) techniques. Finally, we found suitable conditions for synthesis of thin films Zn(O,OH)S to be used as buffer layer in CGS based solar cells.