Batch-Injection Amperometric Determination of Pyrogallol in Biodiesel Using a Multi-Walled Carbon Nanotube Modified Electrode
Autor(a) principal: | |
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Data de Publicação: | 2017 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Journal of the Brazilian Chemical Society (Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532017000901650 |
Resumo: | This work demonstrates the application of batch-injection analysis (BIA) with amperometric detection on a multi-walled carbon nanotube (MWCNT) modified electrode for the sensitive determination of the antioxidant pyrogallol in biodiesel. Samples were diluted in electrolyte (0.1 mol L-1 HClO4) before injection using an electronic micropipette on the BIA cell. The size effect of MWCNTs on electrochemical oxidation of pyrogallol was investigated and 3.5-fold increase in the amperometric sensitivity using the modified electrode with MWCNTs of shorter dimensions was obtained. This result was in agreement with cyclic voltammetry and electrochemical impedance spectroscopy measurements. After optimization of BIA parameters for the amperometric detection on the MWCNT-modified electrode, the proposed method presented a linear range from 0.3 to 1000 µmol L-1, detection limit of 0.013 µmol L-1, precision of 3%, and sample throughput of 240 h-1. Spiked biodiesel samples were analyzed and recovery values between 95-99% were obtained. |
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Journal of the Brazilian Chemical Society (Online) |
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Batch-Injection Amperometric Determination of Pyrogallol in Biodiesel Using a Multi-Walled Carbon Nanotube Modified Electrodeamperometrybiofuelcarbon nanotubeselectrocatalysisphenolic compoundsThis work demonstrates the application of batch-injection analysis (BIA) with amperometric detection on a multi-walled carbon nanotube (MWCNT) modified electrode for the sensitive determination of the antioxidant pyrogallol in biodiesel. Samples were diluted in electrolyte (0.1 mol L-1 HClO4) before injection using an electronic micropipette on the BIA cell. The size effect of MWCNTs on electrochemical oxidation of pyrogallol was investigated and 3.5-fold increase in the amperometric sensitivity using the modified electrode with MWCNTs of shorter dimensions was obtained. This result was in agreement with cyclic voltammetry and electrochemical impedance spectroscopy measurements. After optimization of BIA parameters for the amperometric detection on the MWCNT-modified electrode, the proposed method presented a linear range from 0.3 to 1000 µmol L-1, detection limit of 0.013 µmol L-1, precision of 3%, and sample throughput of 240 h-1. Spiked biodiesel samples were analyzed and recovery values between 95-99% were obtained.Sociedade Brasileira de Química2017-09-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532017000901650Journal of the Brazilian Chemical Society v.28 n.9 2017reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.21577/0103-5053.20160316info:eu-repo/semantics/openAccessCardoso,Rafael M.Dornellas,Rafael M.Lima,Ana P.Montes,Rodrigo H. O.Richter,Eduardo M.Munoz,Rodrigo A. A.eng2017-07-28T00:00:00Zoai:scielo:S0103-50532017000901650Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2017-07-28T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false |
dc.title.none.fl_str_mv |
Batch-Injection Amperometric Determination of Pyrogallol in Biodiesel Using a Multi-Walled Carbon Nanotube Modified Electrode |
title |
Batch-Injection Amperometric Determination of Pyrogallol in Biodiesel Using a Multi-Walled Carbon Nanotube Modified Electrode |
spellingShingle |
Batch-Injection Amperometric Determination of Pyrogallol in Biodiesel Using a Multi-Walled Carbon Nanotube Modified Electrode Cardoso,Rafael M. amperometry biofuel carbon nanotubes electrocatalysis phenolic compounds |
title_short |
Batch-Injection Amperometric Determination of Pyrogallol in Biodiesel Using a Multi-Walled Carbon Nanotube Modified Electrode |
title_full |
Batch-Injection Amperometric Determination of Pyrogallol in Biodiesel Using a Multi-Walled Carbon Nanotube Modified Electrode |
title_fullStr |
Batch-Injection Amperometric Determination of Pyrogallol in Biodiesel Using a Multi-Walled Carbon Nanotube Modified Electrode |
title_full_unstemmed |
Batch-Injection Amperometric Determination of Pyrogallol in Biodiesel Using a Multi-Walled Carbon Nanotube Modified Electrode |
title_sort |
Batch-Injection Amperometric Determination of Pyrogallol in Biodiesel Using a Multi-Walled Carbon Nanotube Modified Electrode |
author |
Cardoso,Rafael M. |
author_facet |
Cardoso,Rafael M. Dornellas,Rafael M. Lima,Ana P. Montes,Rodrigo H. O. Richter,Eduardo M. Munoz,Rodrigo A. A. |
author_role |
author |
author2 |
Dornellas,Rafael M. Lima,Ana P. Montes,Rodrigo H. O. Richter,Eduardo M. Munoz,Rodrigo A. A. |
author2_role |
author author author author author |
dc.contributor.author.fl_str_mv |
Cardoso,Rafael M. Dornellas,Rafael M. Lima,Ana P. Montes,Rodrigo H. O. Richter,Eduardo M. Munoz,Rodrigo A. A. |
dc.subject.por.fl_str_mv |
amperometry biofuel carbon nanotubes electrocatalysis phenolic compounds |
topic |
amperometry biofuel carbon nanotubes electrocatalysis phenolic compounds |
description |
This work demonstrates the application of batch-injection analysis (BIA) with amperometric detection on a multi-walled carbon nanotube (MWCNT) modified electrode for the sensitive determination of the antioxidant pyrogallol in biodiesel. Samples were diluted in electrolyte (0.1 mol L-1 HClO4) before injection using an electronic micropipette on the BIA cell. The size effect of MWCNTs on electrochemical oxidation of pyrogallol was investigated and 3.5-fold increase in the amperometric sensitivity using the modified electrode with MWCNTs of shorter dimensions was obtained. This result was in agreement with cyclic voltammetry and electrochemical impedance spectroscopy measurements. After optimization of BIA parameters for the amperometric detection on the MWCNT-modified electrode, the proposed method presented a linear range from 0.3 to 1000 µmol L-1, detection limit of 0.013 µmol L-1, precision of 3%, and sample throughput of 240 h-1. Spiked biodiesel samples were analyzed and recovery values between 95-99% were obtained. |
publishDate |
2017 |
dc.date.none.fl_str_mv |
2017-09-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532017000901650 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532017000901650 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.21577/0103-5053.20160316 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
dc.source.none.fl_str_mv |
Journal of the Brazilian Chemical Society v.28 n.9 2017 reponame:Journal of the Brazilian Chemical Society (Online) instname:Sociedade Brasileira de Química (SBQ) instacron:SBQ |
instname_str |
Sociedade Brasileira de Química (SBQ) |
instacron_str |
SBQ |
institution |
SBQ |
reponame_str |
Journal of the Brazilian Chemical Society (Online) |
collection |
Journal of the Brazilian Chemical Society (Online) |
repository.name.fl_str_mv |
Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ) |
repository.mail.fl_str_mv |
||office@jbcs.sbq.org.br |
_version_ |
1750318179935059968 |