Modeling of integral reactor applied methane steam reforming - DOI: 10.4025/actascitechnol.v29i2.705

Detalhes bibliográficos
Autor(a) principal: Lenzi, Giane Gonçalves
Data de Publicação: 2008
Outros Autores: Russo, Daniel, Lenzi, Ervin Kaminski, Santos, Onélia Aparecida Andreo dos, Jorge, Luiz Mário de Matos
Tipo de documento: Artigo
Idioma: por
Título da fonte: Acta scientiarum. Technology (Online)
Texto Completo: http://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/705
Resumo: Frequently, the validation of applied mathematical models of industrial reactors dash into the difficulty of obtaining reliable experimental data. A way to overcome this limitation is the proper use and operation or a in bench scale, experimental setup from which experimental data can be obtained in controlled conditions. In this context, experiments were carried out in an integral reactor of steam reform, in different experimental conditions. Thermocouples were placed along the catalyst bed to allow for temperature monitoring in six equally spaced and distinct positions of the reactor, the composition of the effluent of the reactor was determined by gas chromatography. These experimental data were compared with the theoretical results of a pseudo-homogeneous one-dimensional, dynamic mathematical model. The results indicate that the model can successfully describe the experimental data set and the catalytic activity and the conversion are sensitive to variations of the operational temperature, while the temperature of the bed is practically constant to the flow variations in the explored experimental conditions.
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spelling Modeling of integral reactor applied methane steam reforming - DOI: 10.4025/actascitechnol.v29i2.705Modelagem de um reator integral aplicado na reação de reforma a vapor de metano - DOI: 10.4025/actascitechnol.v29i2.705gás de síntesereforma a vapor de metanomodelo matemático3.06.00.00-6 Engenharia QuímicaFrequently, the validation of applied mathematical models of industrial reactors dash into the difficulty of obtaining reliable experimental data. A way to overcome this limitation is the proper use and operation or a in bench scale, experimental setup from which experimental data can be obtained in controlled conditions. In this context, experiments were carried out in an integral reactor of steam reform, in different experimental conditions. Thermocouples were placed along the catalyst bed to allow for temperature monitoring in six equally spaced and distinct positions of the reactor, the composition of the effluent of the reactor was determined by gas chromatography. These experimental data were compared with the theoretical results of a pseudo-homogeneous one-dimensional, dynamic mathematical model. The results indicate that the model can successfully describe the experimental data set and the catalytic activity and the conversion are sensitive to variations of the operational temperature, while the temperature of the bed is practically constant to the flow variations in the explored experimental conditions.Freqüentemente, a validação de modelos matemáticos aplicados a reatores industriais esbarra na dificuldade de obtenção de medidas experimentais confiáveis. Uma maneira de contornar esta limitação corresponde à implantação de uma unidade em escala de bancada devidamente instrumentada, na qual são obtidos dados experimentais em condições controladas. Neste contexto, foram efetuados ensaios em um reator integral de reforma a vapor de metano em escala de bancada, em diversas condições experimentais. As medidas de temperatura no leito foram efetuadas por meio de um termopar multiponto em seis posições axiais distintas, enquanto a composição do efluente do reator foi determinada por cromatografia gasosa. Estes dados experimentais foram comparados com as previsões de um modelo pseudo-homogêneo, unidimensional e dinâmico. Os resultados indicam que o modelo é adequado, sendo que tanto a atividade catalítica como a conversão são sensíveis à temperatura operacional, enquanto a temperatura do leito é praticamente insensível à vazão nas condições experimentais exploradas.Universidade Estadual De Maringá2008-02-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttp://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/70510.4025/actascitechnol.v29i2.705Acta Scientiarum. Technology; Vol 29 No 2 (2007); 181-185Acta Scientiarum. Technology; v. 29 n. 2 (2007); 181-1851806-25631807-8664reponame:Acta scientiarum. Technology (Online)instname:Universidade Estadual de Maringá (UEM)instacron:UEMporhttp://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/705/369Lenzi, Giane GonçalvesRusso, DanielLenzi, Ervin KaminskiSantos, Onélia Aparecida Andreo dosJorge, Luiz Mário de Matosinfo:eu-repo/semantics/openAccess2024-05-17T13:02:29Zoai:periodicos.uem.br/ojs:article/705Revistahttps://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/indexPUBhttps://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/oai||actatech@uem.br1807-86641806-2563opendoar:2024-05-17T13:02:29Acta scientiarum. Technology (Online) - Universidade Estadual de Maringá (UEM)false
dc.title.none.fl_str_mv Modeling of integral reactor applied methane steam reforming - DOI: 10.4025/actascitechnol.v29i2.705
Modelagem de um reator integral aplicado na reação de reforma a vapor de metano - DOI: 10.4025/actascitechnol.v29i2.705
title Modeling of integral reactor applied methane steam reforming - DOI: 10.4025/actascitechnol.v29i2.705
spellingShingle Modeling of integral reactor applied methane steam reforming - DOI: 10.4025/actascitechnol.v29i2.705
Lenzi, Giane Gonçalves
gás de síntese
reforma a vapor de metano
modelo matemático
3.06.00.00-6 Engenharia Química
title_short Modeling of integral reactor applied methane steam reforming - DOI: 10.4025/actascitechnol.v29i2.705
title_full Modeling of integral reactor applied methane steam reforming - DOI: 10.4025/actascitechnol.v29i2.705
title_fullStr Modeling of integral reactor applied methane steam reforming - DOI: 10.4025/actascitechnol.v29i2.705
title_full_unstemmed Modeling of integral reactor applied methane steam reforming - DOI: 10.4025/actascitechnol.v29i2.705
title_sort Modeling of integral reactor applied methane steam reforming - DOI: 10.4025/actascitechnol.v29i2.705
author Lenzi, Giane Gonçalves
author_facet Lenzi, Giane Gonçalves
Russo, Daniel
Lenzi, Ervin Kaminski
Santos, Onélia Aparecida Andreo dos
Jorge, Luiz Mário de Matos
author_role author
author2 Russo, Daniel
Lenzi, Ervin Kaminski
Santos, Onélia Aparecida Andreo dos
Jorge, Luiz Mário de Matos
author2_role author
author
author
author
dc.contributor.author.fl_str_mv Lenzi, Giane Gonçalves
Russo, Daniel
Lenzi, Ervin Kaminski
Santos, Onélia Aparecida Andreo dos
Jorge, Luiz Mário de Matos
dc.subject.por.fl_str_mv gás de síntese
reforma a vapor de metano
modelo matemático
3.06.00.00-6 Engenharia Química
topic gás de síntese
reforma a vapor de metano
modelo matemático
3.06.00.00-6 Engenharia Química
description Frequently, the validation of applied mathematical models of industrial reactors dash into the difficulty of obtaining reliable experimental data. A way to overcome this limitation is the proper use and operation or a in bench scale, experimental setup from which experimental data can be obtained in controlled conditions. In this context, experiments were carried out in an integral reactor of steam reform, in different experimental conditions. Thermocouples were placed along the catalyst bed to allow for temperature monitoring in six equally spaced and distinct positions of the reactor, the composition of the effluent of the reactor was determined by gas chromatography. These experimental data were compared with the theoretical results of a pseudo-homogeneous one-dimensional, dynamic mathematical model. The results indicate that the model can successfully describe the experimental data set and the catalytic activity and the conversion are sensitive to variations of the operational temperature, while the temperature of the bed is practically constant to the flow variations in the explored experimental conditions.
publishDate 2008
dc.date.none.fl_str_mv 2008-02-12
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
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format article
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dc.identifier.uri.fl_str_mv http://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/705
10.4025/actascitechnol.v29i2.705
url http://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/705
identifier_str_mv 10.4025/actascitechnol.v29i2.705
dc.language.iso.fl_str_mv por
language por
dc.relation.none.fl_str_mv http://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/705/369
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Universidade Estadual De Maringá
publisher.none.fl_str_mv Universidade Estadual De Maringá
dc.source.none.fl_str_mv Acta Scientiarum. Technology; Vol 29 No 2 (2007); 181-185
Acta Scientiarum. Technology; v. 29 n. 2 (2007); 181-185
1806-2563
1807-8664
reponame:Acta scientiarum. Technology (Online)
instname:Universidade Estadual de Maringá (UEM)
instacron:UEM
instname_str Universidade Estadual de Maringá (UEM)
instacron_str UEM
institution UEM
reponame_str Acta scientiarum. Technology (Online)
collection Acta scientiarum. Technology (Online)
repository.name.fl_str_mv Acta scientiarum. Technology (Online) - Universidade Estadual de Maringá (UEM)
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