Modeling of integral reactor applied methane steam reforming - DOI: 10.4025/actascitechnol.v29i2.705
Autor(a) principal: | |
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Data de Publicação: | 2008 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | por |
Título da fonte: | Acta scientiarum. Technology (Online) |
Texto Completo: | http://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/705 |
Resumo: | Frequently, the validation of applied mathematical models of industrial reactors dash into the difficulty of obtaining reliable experimental data. A way to overcome this limitation is the proper use and operation or a in bench scale, experimental setup from which experimental data can be obtained in controlled conditions. In this context, experiments were carried out in an integral reactor of steam reform, in different experimental conditions. Thermocouples were placed along the catalyst bed to allow for temperature monitoring in six equally spaced and distinct positions of the reactor, the composition of the effluent of the reactor was determined by gas chromatography. These experimental data were compared with the theoretical results of a pseudo-homogeneous one-dimensional, dynamic mathematical model. The results indicate that the model can successfully describe the experimental data set and the catalytic activity and the conversion are sensitive to variations of the operational temperature, while the temperature of the bed is practically constant to the flow variations in the explored experimental conditions. |
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Modeling of integral reactor applied methane steam reforming - DOI: 10.4025/actascitechnol.v29i2.705Modelagem de um reator integral aplicado na reação de reforma a vapor de metano - DOI: 10.4025/actascitechnol.v29i2.705gás de síntesereforma a vapor de metanomodelo matemático3.06.00.00-6 Engenharia QuímicaFrequently, the validation of applied mathematical models of industrial reactors dash into the difficulty of obtaining reliable experimental data. A way to overcome this limitation is the proper use and operation or a in bench scale, experimental setup from which experimental data can be obtained in controlled conditions. In this context, experiments were carried out in an integral reactor of steam reform, in different experimental conditions. Thermocouples were placed along the catalyst bed to allow for temperature monitoring in six equally spaced and distinct positions of the reactor, the composition of the effluent of the reactor was determined by gas chromatography. These experimental data were compared with the theoretical results of a pseudo-homogeneous one-dimensional, dynamic mathematical model. The results indicate that the model can successfully describe the experimental data set and the catalytic activity and the conversion are sensitive to variations of the operational temperature, while the temperature of the bed is practically constant to the flow variations in the explored experimental conditions.Freqüentemente, a validação de modelos matemáticos aplicados a reatores industriais esbarra na dificuldade de obtenção de medidas experimentais confiáveis. Uma maneira de contornar esta limitação corresponde à implantação de uma unidade em escala de bancada devidamente instrumentada, na qual são obtidos dados experimentais em condições controladas. Neste contexto, foram efetuados ensaios em um reator integral de reforma a vapor de metano em escala de bancada, em diversas condições experimentais. As medidas de temperatura no leito foram efetuadas por meio de um termopar multiponto em seis posições axiais distintas, enquanto a composição do efluente do reator foi determinada por cromatografia gasosa. Estes dados experimentais foram comparados com as previsões de um modelo pseudo-homogêneo, unidimensional e dinâmico. Os resultados indicam que o modelo é adequado, sendo que tanto a atividade catalítica como a conversão são sensíveis à temperatura operacional, enquanto a temperatura do leito é praticamente insensível à vazão nas condições experimentais exploradas.Universidade Estadual De Maringá2008-02-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttp://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/70510.4025/actascitechnol.v29i2.705Acta Scientiarum. Technology; Vol 29 No 2 (2007); 181-185Acta Scientiarum. Technology; v. 29 n. 2 (2007); 181-1851806-25631807-8664reponame:Acta scientiarum. Technology (Online)instname:Universidade Estadual de Maringá (UEM)instacron:UEMporhttp://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/705/369Lenzi, Giane GonçalvesRusso, DanielLenzi, Ervin KaminskiSantos, Onélia Aparecida Andreo dosJorge, Luiz Mário de Matosinfo:eu-repo/semantics/openAccess2024-05-17T13:02:29Zoai:periodicos.uem.br/ojs:article/705Revistahttps://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/indexPUBhttps://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/oai||actatech@uem.br1807-86641806-2563opendoar:2024-05-17T13:02:29Acta scientiarum. Technology (Online) - Universidade Estadual de Maringá (UEM)false |
dc.title.none.fl_str_mv |
Modeling of integral reactor applied methane steam reforming - DOI: 10.4025/actascitechnol.v29i2.705 Modelagem de um reator integral aplicado na reação de reforma a vapor de metano - DOI: 10.4025/actascitechnol.v29i2.705 |
title |
Modeling of integral reactor applied methane steam reforming - DOI: 10.4025/actascitechnol.v29i2.705 |
spellingShingle |
Modeling of integral reactor applied methane steam reforming - DOI: 10.4025/actascitechnol.v29i2.705 Lenzi, Giane Gonçalves gás de síntese reforma a vapor de metano modelo matemático 3.06.00.00-6 Engenharia Química |
title_short |
Modeling of integral reactor applied methane steam reforming - DOI: 10.4025/actascitechnol.v29i2.705 |
title_full |
Modeling of integral reactor applied methane steam reforming - DOI: 10.4025/actascitechnol.v29i2.705 |
title_fullStr |
Modeling of integral reactor applied methane steam reforming - DOI: 10.4025/actascitechnol.v29i2.705 |
title_full_unstemmed |
Modeling of integral reactor applied methane steam reforming - DOI: 10.4025/actascitechnol.v29i2.705 |
title_sort |
Modeling of integral reactor applied methane steam reforming - DOI: 10.4025/actascitechnol.v29i2.705 |
author |
Lenzi, Giane Gonçalves |
author_facet |
Lenzi, Giane Gonçalves Russo, Daniel Lenzi, Ervin Kaminski Santos, Onélia Aparecida Andreo dos Jorge, Luiz Mário de Matos |
author_role |
author |
author2 |
Russo, Daniel Lenzi, Ervin Kaminski Santos, Onélia Aparecida Andreo dos Jorge, Luiz Mário de Matos |
author2_role |
author author author author |
dc.contributor.author.fl_str_mv |
Lenzi, Giane Gonçalves Russo, Daniel Lenzi, Ervin Kaminski Santos, Onélia Aparecida Andreo dos Jorge, Luiz Mário de Matos |
dc.subject.por.fl_str_mv |
gás de síntese reforma a vapor de metano modelo matemático 3.06.00.00-6 Engenharia Química |
topic |
gás de síntese reforma a vapor de metano modelo matemático 3.06.00.00-6 Engenharia Química |
description |
Frequently, the validation of applied mathematical models of industrial reactors dash into the difficulty of obtaining reliable experimental data. A way to overcome this limitation is the proper use and operation or a in bench scale, experimental setup from which experimental data can be obtained in controlled conditions. In this context, experiments were carried out in an integral reactor of steam reform, in different experimental conditions. Thermocouples were placed along the catalyst bed to allow for temperature monitoring in six equally spaced and distinct positions of the reactor, the composition of the effluent of the reactor was determined by gas chromatography. These experimental data were compared with the theoretical results of a pseudo-homogeneous one-dimensional, dynamic mathematical model. The results indicate that the model can successfully describe the experimental data set and the catalytic activity and the conversion are sensitive to variations of the operational temperature, while the temperature of the bed is practically constant to the flow variations in the explored experimental conditions. |
publishDate |
2008 |
dc.date.none.fl_str_mv |
2008-02-12 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/705 10.4025/actascitechnol.v29i2.705 |
url |
http://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/705 |
identifier_str_mv |
10.4025/actascitechnol.v29i2.705 |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.relation.none.fl_str_mv |
http://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/705/369 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Universidade Estadual De Maringá |
publisher.none.fl_str_mv |
Universidade Estadual De Maringá |
dc.source.none.fl_str_mv |
Acta Scientiarum. Technology; Vol 29 No 2 (2007); 181-185 Acta Scientiarum. Technology; v. 29 n. 2 (2007); 181-185 1806-2563 1807-8664 reponame:Acta scientiarum. Technology (Online) instname:Universidade Estadual de Maringá (UEM) instacron:UEM |
instname_str |
Universidade Estadual de Maringá (UEM) |
instacron_str |
UEM |
institution |
UEM |
reponame_str |
Acta scientiarum. Technology (Online) |
collection |
Acta scientiarum. Technology (Online) |
repository.name.fl_str_mv |
Acta scientiarum. Technology (Online) - Universidade Estadual de Maringá (UEM) |
repository.mail.fl_str_mv |
||actatech@uem.br |
_version_ |
1799315331478454272 |