Synthesis and characterization of trans-[Ru(NO)Cl(L)4](PF6)2 (L = isonicotinamide; 4-acetylpyridine) and related species

Detalhes bibliográficos
Autor(a) principal: Calandreli, Ivy
Data de Publicação: 2009
Outros Autores: Oliveira, Fabiana de Souza, Liang, Guogang, Rocha, Zênis Novais da, Tfouni, Elia
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UFBA
Texto Completo: http://www.repositorio.ufba.br/ri/handle/ri/6430
Resumo: Trabalho completo: acesso restrito, p.591–595
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spelling Calandreli, IvyOliveira, Fabiana de SouzaLiang, GuogangRocha, Zênis Novais daTfouni, EliaCalandreli, IvyOliveira, Fabiana de SouzaLiang, GuogangRocha, Zênis Novais daTfouni, Elia2012-07-13T19:14:30Z20091387-7003http://www.repositorio.ufba.br/ri/handle/ri/6430v. 12, n. 7Trabalho completo: acesso restrito, p.591–595he trans-[RuCl2(L)4], trans-[Ru(NO)Cl (L)4](PF6)2 (L = isonicotinamide and 4-acetylpyridine) and trans-[Ru(NO)(OH)(py)4]Cl2 (py = pyridine) complexes have been prepared and characterized by elemental analysis, UV–visible, infrared, and 1H NMR spectroscopies, and cyclic voltammetry. The MLCT band energies of trans-[RuCl2(L)4] increase in the order 4-acpy < isn < py. The reduction potentials of trans-[RuCl2(L)4] and trans-[Ru(NO)Cl(L)4]2+ increase in the order py < isn < 4-acpy. The stretching band frequency, νNO, of the nitrosyl complexes ranges from 1913 to 1852 cm−1 indicating a nitrosonium character for the NO ligand. Due to the large π-acceptor ability of the equatorial ligands, the coordinated water is much more acidic in the water soluble trans-[Ru(NO)(H2O)(py)4]3+ than in trans-[Ru(NO)(H2O)(NH3)4]3+.Submitted by Bruna Lessa (lessbruna@gmail.com) on 2012-07-13T19:14:30Z No. of bitstreams: 1 (119)1-s2.0-S1387700309002196-main.pdf: 646904 bytes, checksum: f94c5d99fca014612bd3991b1cff639f (MD5)Made available in DSpace on 2012-07-13T19:14:30Z (GMT). No. of bitstreams: 1 (119)1-s2.0-S1387700309002196-main.pdf: 646904 bytes, checksum: f94c5d99fca014612bd3991b1cff639f (MD5) Previous issue date: 2009-07Elsevierhttp://dx.doi.org/10.1016/j.inoche.2009.04.024reponame:Repositório Institucional da UFBAinstname:Universidade Federal da Bahia (UFBA)instacron:UFBASynthesis and characterization of trans-[Ru(NO)Cl(L)4](PF6)2 (L = isonicotinamide; 4-acetylpyridine) and related speciesInorganic Chemistry Communicationsinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article10000-01-01enginfo:eu-repo/semantics/openAccessORIGINAL(119)1-s2.0-S1387700309002196-main.pdf(119)1-s2.0-S1387700309002196-main.pdfapplication/pdf646904https://repositorio.ufba.br/bitstream/ri/6430/1/%28119%291-s2.0-S1387700309002196-main.pdff94c5d99fca014612bd3991b1cff639fMD51LICENSElicense.txtlicense.txttext/plain1762https://repositorio.ufba.br/bitstream/ri/6430/2/license.txt1b89a9a0548218172d7c829f87a0eab9MD52ri/64302022-09-13 13:17:30.551oai:repositorio.ufba.br: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Repositório InstitucionalPUBhttp://192.188.11.11:8080/oai/requestopendoar:19322022-09-13T16:17:30Repositório Institucional da UFBA - Universidade Federal da Bahia (UFBA)false
dc.title.pt_BR.fl_str_mv Synthesis and characterization of trans-[Ru(NO)Cl(L)4](PF6)2 (L = isonicotinamide; 4-acetylpyridine) and related species
dc.title.alternative.pt_BR.fl_str_mv Inorganic Chemistry Communications
title Synthesis and characterization of trans-[Ru(NO)Cl(L)4](PF6)2 (L = isonicotinamide; 4-acetylpyridine) and related species
spellingShingle Synthesis and characterization of trans-[Ru(NO)Cl(L)4](PF6)2 (L = isonicotinamide; 4-acetylpyridine) and related species
Calandreli, Ivy
title_short Synthesis and characterization of trans-[Ru(NO)Cl(L)4](PF6)2 (L = isonicotinamide; 4-acetylpyridine) and related species
title_full Synthesis and characterization of trans-[Ru(NO)Cl(L)4](PF6)2 (L = isonicotinamide; 4-acetylpyridine) and related species
title_fullStr Synthesis and characterization of trans-[Ru(NO)Cl(L)4](PF6)2 (L = isonicotinamide; 4-acetylpyridine) and related species
title_full_unstemmed Synthesis and characterization of trans-[Ru(NO)Cl(L)4](PF6)2 (L = isonicotinamide; 4-acetylpyridine) and related species
title_sort Synthesis and characterization of trans-[Ru(NO)Cl(L)4](PF6)2 (L = isonicotinamide; 4-acetylpyridine) and related species
author Calandreli, Ivy
author_facet Calandreli, Ivy
Oliveira, Fabiana de Souza
Liang, Guogang
Rocha, Zênis Novais da
Tfouni, Elia
author_role author
author2 Oliveira, Fabiana de Souza
Liang, Guogang
Rocha, Zênis Novais da
Tfouni, Elia
author2_role author
author
author
author
dc.contributor.author.fl_str_mv Calandreli, Ivy
Oliveira, Fabiana de Souza
Liang, Guogang
Rocha, Zênis Novais da
Tfouni, Elia
Calandreli, Ivy
Oliveira, Fabiana de Souza
Liang, Guogang
Rocha, Zênis Novais da
Tfouni, Elia
description Trabalho completo: acesso restrito, p.591–595
publishDate 2009
dc.date.issued.fl_str_mv 2009
dc.date.accessioned.fl_str_mv 2012-07-13T19:14:30Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://www.repositorio.ufba.br/ri/handle/ri/6430
dc.identifier.issn.none.fl_str_mv 1387-7003
dc.identifier.number.pt_BR.fl_str_mv v. 12, n. 7
identifier_str_mv 1387-7003
v. 12, n. 7
url http://www.repositorio.ufba.br/ri/handle/ri/6430
dc.language.iso.fl_str_mv eng
language eng
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.pt_BR.fl_str_mv http://dx.doi.org/10.1016/j.inoche.2009.04.024
dc.source.none.fl_str_mv reponame:Repositório Institucional da UFBA
instname:Universidade Federal da Bahia (UFBA)
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instname_str Universidade Federal da Bahia (UFBA)
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institution UFBA
reponame_str Repositório Institucional da UFBA
collection Repositório Institucional da UFBA
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