Novas abordagens para otimizar a funcionalidade de recobrimentos à base de amido para manter a qualidade e conservação pós-colheita de frutos tropicais.

Detalhes bibliográficos
Autor(a) principal: Lima, Renato Pereira
Data de Publicação: 2020
Tipo de documento: Tese
Idioma: por
Título da fonte: Biblioteca Digital de Teses e Dissertações da UFPB
Texto Completo: https://repositorio.ufpb.br/jspui/handle/123456789/18382
Resumo: This work was aimed at optimizing the functionality of starch-based coatings for maintaining quality and improving postharvest conservation of tropical fruits. The coatings studied were based on cassava flour (starch). Four experimental approaches were carried out: I – Propose a method to estimate the proportion of the surface with starch-based coatings, using digital processing of iodine-stained fruit images, and optimize the potential of the coating to adhere to the surface of different fruits; II – Develop a non-destructive method to estimate the diffusion of gases through a coated fruit surface, and study the impact of the coating-epidermis/gas exchange resistance on the composition of the coated papaya's internal atmosphere (atmi ); III – Monitor the internal O2 and CO2 concentrations in coated banana in relation to the proportion of the coated surface and the atmi composition; IV – To evaluate the effects of combined coating with deep eutectic solvent (NADES) of ascorbic acid /choline chloride as a plasticizer on postharvest quality of mango. The main results were: I – Coatings ability to adhere on different fruit surfaces were improved by adding surfactant and increasing starch concentration in the dispersions. Adding Tween 40 in a cooled (18 oC) dispersion resulted in coating with high ability to adhere to the surface of different fruits (mandarin, pepper, banana and papaya), leading to a blockage of the pores, which may be due to the increased adsorption of the coating to the fruit’ surfaces without decreasing amylose-amylose interactions. II – The quantification of the resistance to the diffusion of gases through the fruit’ surface can be useful in defining the target atmi in coated fruits, especially considering the interaction between the coating and the peel. In defining changes in the composition of the atmi , the resistance to gas diffusion was the most appropriate variable than the respiratory rate. III – A 3.0%-starch coated the entire banana surface and resulted in anaerobiosis, indicated by a too low P i O2 and a burst in P i CO2 and increased respiratory quotient. The P i O2 of 6 kPa in chambers attached on the fruit skin was the indicative of an adequate atmi was set for starch coated bananas, at which respiratory rate was minimized without development of anaerobiosis. Based on that, 1.5 and 2.0% starch coatings might be effective for delaying ripening, maintaining qualities, and extend shelf life of bananas. A proportion of 75% of coated surface was estimated as the limit for secure modified atmosphere for bananas. IV – The P i O2 immediately beneath the coated skin was much lower in mangoes coated with starch + NADES compared to those with starch + glycerol and those not coated. The atmi ensured by starch + NADES coating was effective in delaying mango ripening and maintaining the superior quality in relation to the other coatings. In addition, mangos with starch + NADES prevented and / or reduced the damage induced by ROS, maintaining a higher content of ascorbic acid and balanced SOD, POD and APX activities compared to those with starch + glycerol and those not coated during storage.
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spelling Novas abordagens para otimizar a funcionalidade de recobrimentos à base de amido para manter a qualidade e conservação pós-colheita de frutos tropicais.Atmosfera modificada.Mamão.Banana.Manga.Solvente eutético profundo.Atmosfera interna.CNPQ::CIENCIAS AGRARIAS::AGRONOMIAThis work was aimed at optimizing the functionality of starch-based coatings for maintaining quality and improving postharvest conservation of tropical fruits. The coatings studied were based on cassava flour (starch). Four experimental approaches were carried out: I – Propose a method to estimate the proportion of the surface with starch-based coatings, using digital processing of iodine-stained fruit images, and optimize the potential of the coating to adhere to the surface of different fruits; II – Develop a non-destructive method to estimate the diffusion of gases through a coated fruit surface, and study the impact of the coating-epidermis/gas exchange resistance on the composition of the coated papaya's internal atmosphere (atmi ); III – Monitor the internal O2 and CO2 concentrations in coated banana in relation to the proportion of the coated surface and the atmi composition; IV – To evaluate the effects of combined coating with deep eutectic solvent (NADES) of ascorbic acid /choline chloride as a plasticizer on postharvest quality of mango. The main results were: I – Coatings ability to adhere on different fruit surfaces were improved by adding surfactant and increasing starch concentration in the dispersions. Adding Tween 40 in a cooled (18 oC) dispersion resulted in coating with high ability to adhere to the surface of different fruits (mandarin, pepper, banana and papaya), leading to a blockage of the pores, which may be due to the increased adsorption of the coating to the fruit’ surfaces without decreasing amylose-amylose interactions. II – The quantification of the resistance to the diffusion of gases through the fruit’ surface can be useful in defining the target atmi in coated fruits, especially considering the interaction between the coating and the peel. In defining changes in the composition of the atmi , the resistance to gas diffusion was the most appropriate variable than the respiratory rate. III – A 3.0%-starch coated the entire banana surface and resulted in anaerobiosis, indicated by a too low P i O2 and a burst in P i CO2 and increased respiratory quotient. The P i O2 of 6 kPa in chambers attached on the fruit skin was the indicative of an adequate atmi was set for starch coated bananas, at which respiratory rate was minimized without development of anaerobiosis. Based on that, 1.5 and 2.0% starch coatings might be effective for delaying ripening, maintaining qualities, and extend shelf life of bananas. A proportion of 75% of coated surface was estimated as the limit for secure modified atmosphere for bananas. IV – The P i O2 immediately beneath the coated skin was much lower in mangoes coated with starch + NADES compared to those with starch + glycerol and those not coated. The atmi ensured by starch + NADES coating was effective in delaying mango ripening and maintaining the superior quality in relation to the other coatings. In addition, mangos with starch + NADES prevented and / or reduced the damage induced by ROS, maintaining a higher content of ascorbic acid and balanced SOD, POD and APX activities compared to those with starch + glycerol and those not coated during storage.Esta pesquisa teve como objetivo otimizar a funcionalidade de recobrimentos à base de amido para manter a qualidade e aumentar a conservação pós-colheita de frutos tropicais. Os recobrimentos estudados foram à base de fácula de mandioca (amido). Foram realizadas quatro abordagens experimentais: I - Propor um método para estimar a proporção da superfície com recobrimentos à base de amido utilizando processamento digital de imagens de frutos corados com iodo, e otimizar o potencial do recobrimento em aderir a superfície de diferentes frutos; II - Desenvolver um método não destrutivo para estimar a difusão de gases através da superfície do fruto recoberto, e estudar o impacto da interação recobrimento-epiderme/resistência às trocas gasosas na composição da atmosfera interna (atmi ) do mamão; III - Monitorar as concentrações internas de O2 e CO2 em banana recobertas em relação à proporção da superfície recoberta e à composição da atmi ; IV - Avaliar os efeitos do recobrimento combinado com solvente eutético profundo (NADES) de ácido ascórbico/cloreto de colina na qualidade pós-colheita de manga. Os principais resultados foram: I - A capacidade do recobrimento em aderir a diferentes superfícies de frutos foi otimizada pela adição de surfactante e o aumento da concentração nas dispersões. A adição de Tween 40 na dispersão resfriada (18 oC) resultou em recobrimentos com alta capacidade de aderência à superfície de diferentes de frutos (tangerina, pimenta, banana e mamão), que pode ser devido ao aumento da adsorção do recobrimento às superfícies dos frutos sem diminuir as interações amilose-amilose. II – A quantificação da resistência à difusão de gases através da superfície pode ser útil em definir a atmi alvo em frutos recobertos, especialmente considerando a interação entre o recobrimento e a casca. Na definição das mudanças na composição da atmi , a resistência à difusão de gases foi a variável mais apropriada do que a taxa respiratória. III - O nível de 3,0% de amido cobriu toda a superfície da banana e resultou em anaerobiose, indicada pela P i O2 muito baixa, P i CO2 muito alta e aumento do quociente respiratório. A P i O2 de 6 kPa em câmaras fixadas na casca foi o indicativo de que uma atmi adequada foi atingida nas bananas recobertas, cuja taxa respiratória foi minimizada, sem resultar em anaerobiose. Com base nisso, as concentrações de 1,5 e 2,0% de amido podem ser eficazes em retardar a maturação, manter a qualidade e estender a vida útil de banana. A proporção de 75% da superfície recoberta foi estimada como o limite para uma atmosfera modificada segura para bananas. IV - A P i O2 imediatamente abaixo da casca foi bem menor em mangas recobertas com amido+NADES comparadas com as com amido+glicerol e as não recobertas. A atmi garantida pelo amido+NADES foi eficaz em retardar o amadurecimento da manga e manter a qualidade superior em relação aos demais recobrimentos. Além disso, mangas com amido+NADES preveniu e/ou reduziu os danos induzidos por ROS, mantendo maior teor de ácido ascórbico e atividades SOD, POD e APX balanceadas em comparação com as com amido+glicerol e as não recobertas durante o armazenamento.Universidade Federal da ParaíbaBrasilQuímica e FísicaPrograma de Pós-Graduação em AgronomiaUFPBSilva, Silvanda de Melohttp://lattes.cnpq.br/0537577552100520Beaudry, Randolph M.http://lattes.cnpq.br/1286326411534305Lima, Renato Pereira2020-11-10T15:04:46Z2020-11-102020-11-10T15:04:46Z2020-02-28info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/doctoralThesishttps://repositorio.ufpb.br/jspui/handle/123456789/18382porAttribution-NoDerivs 3.0 Brazilhttp://creativecommons.org/licenses/by-nd/3.0/br/info:eu-repo/semantics/openAccessreponame:Biblioteca Digital de Teses e Dissertações da UFPBinstname:Universidade Federal da Paraíba (UFPB)instacron:UFPB2020-11-11T06:17:35Zoai:repositorio.ufpb.br:123456789/18382Biblioteca Digital de Teses e Dissertaçõeshttps://repositorio.ufpb.br/PUBhttp://tede.biblioteca.ufpb.br:8080/oai/requestdiretoria@ufpb.br|| diretoria@ufpb.bropendoar:2020-11-11T06:17:35Biblioteca Digital de Teses e Dissertações da UFPB - Universidade Federal da Paraíba (UFPB)false
dc.title.none.fl_str_mv Novas abordagens para otimizar a funcionalidade de recobrimentos à base de amido para manter a qualidade e conservação pós-colheita de frutos tropicais.
title Novas abordagens para otimizar a funcionalidade de recobrimentos à base de amido para manter a qualidade e conservação pós-colheita de frutos tropicais.
spellingShingle Novas abordagens para otimizar a funcionalidade de recobrimentos à base de amido para manter a qualidade e conservação pós-colheita de frutos tropicais.
Lima, Renato Pereira
Atmosfera modificada.
Mamão.
Banana.
Manga.
Solvente eutético profundo.
Atmosfera interna.
CNPQ::CIENCIAS AGRARIAS::AGRONOMIA
title_short Novas abordagens para otimizar a funcionalidade de recobrimentos à base de amido para manter a qualidade e conservação pós-colheita de frutos tropicais.
title_full Novas abordagens para otimizar a funcionalidade de recobrimentos à base de amido para manter a qualidade e conservação pós-colheita de frutos tropicais.
title_fullStr Novas abordagens para otimizar a funcionalidade de recobrimentos à base de amido para manter a qualidade e conservação pós-colheita de frutos tropicais.
title_full_unstemmed Novas abordagens para otimizar a funcionalidade de recobrimentos à base de amido para manter a qualidade e conservação pós-colheita de frutos tropicais.
title_sort Novas abordagens para otimizar a funcionalidade de recobrimentos à base de amido para manter a qualidade e conservação pós-colheita de frutos tropicais.
author Lima, Renato Pereira
author_facet Lima, Renato Pereira
author_role author
dc.contributor.none.fl_str_mv Silva, Silvanda de Melo
http://lattes.cnpq.br/0537577552100520
Beaudry, Randolph M.
http://lattes.cnpq.br/1286326411534305
dc.contributor.author.fl_str_mv Lima, Renato Pereira
dc.subject.por.fl_str_mv Atmosfera modificada.
Mamão.
Banana.
Manga.
Solvente eutético profundo.
Atmosfera interna.
CNPQ::CIENCIAS AGRARIAS::AGRONOMIA
topic Atmosfera modificada.
Mamão.
Banana.
Manga.
Solvente eutético profundo.
Atmosfera interna.
CNPQ::CIENCIAS AGRARIAS::AGRONOMIA
description This work was aimed at optimizing the functionality of starch-based coatings for maintaining quality and improving postharvest conservation of tropical fruits. The coatings studied were based on cassava flour (starch). Four experimental approaches were carried out: I – Propose a method to estimate the proportion of the surface with starch-based coatings, using digital processing of iodine-stained fruit images, and optimize the potential of the coating to adhere to the surface of different fruits; II – Develop a non-destructive method to estimate the diffusion of gases through a coated fruit surface, and study the impact of the coating-epidermis/gas exchange resistance on the composition of the coated papaya's internal atmosphere (atmi ); III – Monitor the internal O2 and CO2 concentrations in coated banana in relation to the proportion of the coated surface and the atmi composition; IV – To evaluate the effects of combined coating with deep eutectic solvent (NADES) of ascorbic acid /choline chloride as a plasticizer on postharvest quality of mango. The main results were: I – Coatings ability to adhere on different fruit surfaces were improved by adding surfactant and increasing starch concentration in the dispersions. Adding Tween 40 in a cooled (18 oC) dispersion resulted in coating with high ability to adhere to the surface of different fruits (mandarin, pepper, banana and papaya), leading to a blockage of the pores, which may be due to the increased adsorption of the coating to the fruit’ surfaces without decreasing amylose-amylose interactions. II – The quantification of the resistance to the diffusion of gases through the fruit’ surface can be useful in defining the target atmi in coated fruits, especially considering the interaction between the coating and the peel. In defining changes in the composition of the atmi , the resistance to gas diffusion was the most appropriate variable than the respiratory rate. III – A 3.0%-starch coated the entire banana surface and resulted in anaerobiosis, indicated by a too low P i O2 and a burst in P i CO2 and increased respiratory quotient. The P i O2 of 6 kPa in chambers attached on the fruit skin was the indicative of an adequate atmi was set for starch coated bananas, at which respiratory rate was minimized without development of anaerobiosis. Based on that, 1.5 and 2.0% starch coatings might be effective for delaying ripening, maintaining qualities, and extend shelf life of bananas. A proportion of 75% of coated surface was estimated as the limit for secure modified atmosphere for bananas. IV – The P i O2 immediately beneath the coated skin was much lower in mangoes coated with starch + NADES compared to those with starch + glycerol and those not coated. The atmi ensured by starch + NADES coating was effective in delaying mango ripening and maintaining the superior quality in relation to the other coatings. In addition, mangos with starch + NADES prevented and / or reduced the damage induced by ROS, maintaining a higher content of ascorbic acid and balanced SOD, POD and APX activities compared to those with starch + glycerol and those not coated during storage.
publishDate 2020
dc.date.none.fl_str_mv 2020-11-10T15:04:46Z
2020-11-10
2020-11-10T15:04:46Z
2020-02-28
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/doctoralThesis
format doctoralThesis
status_str publishedVersion
dc.identifier.uri.fl_str_mv https://repositorio.ufpb.br/jspui/handle/123456789/18382
url https://repositorio.ufpb.br/jspui/handle/123456789/18382
dc.language.iso.fl_str_mv por
language por
dc.rights.driver.fl_str_mv Attribution-NoDerivs 3.0 Brazil
http://creativecommons.org/licenses/by-nd/3.0/br/
info:eu-repo/semantics/openAccess
rights_invalid_str_mv Attribution-NoDerivs 3.0 Brazil
http://creativecommons.org/licenses/by-nd/3.0/br/
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Universidade Federal da Paraíba
Brasil
Química e Física
Programa de Pós-Graduação em Agronomia
UFPB
publisher.none.fl_str_mv Universidade Federal da Paraíba
Brasil
Química e Física
Programa de Pós-Graduação em Agronomia
UFPB
dc.source.none.fl_str_mv reponame:Biblioteca Digital de Teses e Dissertações da UFPB
instname:Universidade Federal da Paraíba (UFPB)
instacron:UFPB
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reponame_str Biblioteca Digital de Teses e Dissertações da UFPB
collection Biblioteca Digital de Teses e Dissertações da UFPB
repository.name.fl_str_mv Biblioteca Digital de Teses e Dissertações da UFPB - Universidade Federal da Paraíba (UFPB)
repository.mail.fl_str_mv diretoria@ufpb.br|| diretoria@ufpb.br
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