Investigation of indirect structural and chemical parameters of GeSi nanoparticles in a silica matrix by combined synchrotron radiation techniques

Detalhes bibliográficos
Autor(a) principal: Gasperini, A. A. M.
Data de Publicação: 2012
Outros Autores: Malachias, A., Fabbris, Gilberto Fernandes Lopes, Kellermann, Guinter, Gobbi, Angelo Luiz, Avendaño Soto, E., Azevedo, Gustavo de Medeiros
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UFRGS
Texto Completo: http://hdl.handle.net/10183/89685
Resumo: The formation of GeSi nanoparticles on an SiO2 matrix is studied here by synchrotron-based techniques. The shape, average diameter and size dispersion were obtained from grazing-incidence small-angle X-ray scattering data. X-ray diffraction measurements were used to obtain crystallite sizes and composition via resonant (anomalous) measurements. By using these techniques as input for extended X-ray absorption fine structure analysis, the local composition surrounding the Ge atoms is investigated. Although the results for each of the methods above are commonly analyzed separately, the combination of such techniques leads to an improved understanding of nanoparticle structural and chemical properties. Crucial indirect parameters that cannot be quantified by other means are accessed in this work, such as local strain, the possibility of forming core–shell structures, the fraction of Ge atoms diluted in the matrix (not forming nanoparticles), the amorphous and crystalline Ge fractions, and the relative population of nanoparticles with single and multiple crystalline domains.
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spelling Gasperini, A. A. M.Malachias, A.Fabbris, Gilberto Fernandes LopesKellermann, GuinterGobbi, Angelo LuizAvendaño Soto, E.Azevedo, Gustavo de Medeiros2014-03-26T01:50:56Z20120021-8898http://hdl.handle.net/10183/89685000820137The formation of GeSi nanoparticles on an SiO2 matrix is studied here by synchrotron-based techniques. The shape, average diameter and size dispersion were obtained from grazing-incidence small-angle X-ray scattering data. X-ray diffraction measurements were used to obtain crystallite sizes and composition via resonant (anomalous) measurements. By using these techniques as input for extended X-ray absorption fine structure analysis, the local composition surrounding the Ge atoms is investigated. Although the results for each of the methods above are commonly analyzed separately, the combination of such techniques leads to an improved understanding of nanoparticle structural and chemical properties. Crucial indirect parameters that cannot be quantified by other means are accessed in this work, such as local strain, the possibility of forming core–shell structures, the fraction of Ge atoms diluted in the matrix (not forming nanoparticles), the amorphous and crystalline Ge fractions, and the relative population of nanoparticles with single and multiple crystalline domains.application/pdfengJournal of Applied Crystallography. Copenhagen. Vol. 45, no. 1 (Feb. 2012), p. 71-84Materiais semicondutoresCrescimento de semicondutoresNanopartículasAnálise químicaEspalhamento de raios-xEstrutura fina estendida de absorção de raios x (EXAFS)Compostos de silícioInvestigation of indirect structural and chemical parameters of GeSi nanoparticles in a silica matrix by combined synchrotron radiation techniquesEstrangeiroinfo:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da UFRGSinstname:Universidade Federal do Rio Grande do Sul (UFRGS)instacron:UFRGSORIGINAL000820137.pdf000820137.pdfTexto completo (inglês)application/pdf1434929http://www.lume.ufrgs.br/bitstream/10183/89685/1/000820137.pdf926f7afc1fd4a33a824362dce5dc4ed8MD51TEXT000820137.pdf.txt000820137.pdf.txtExtracted Texttext/plain72354http://www.lume.ufrgs.br/bitstream/10183/89685/2/000820137.pdf.txtc98a5ca838f0af8ce35f25510d96abf3MD52THUMBNAIL000820137.pdf.jpg000820137.pdf.jpgGenerated Thumbnailimage/jpeg2035http://www.lume.ufrgs.br/bitstream/10183/89685/3/000820137.pdf.jpg0c3f4eaf7a5256786444ab7a7a5d3b50MD5310183/896852020-11-26 05:15:59.092454oai:www.lume.ufrgs.br:10183/89685Repositório de PublicaçõesPUBhttps://lume.ufrgs.br/oai/requestopendoar:2020-11-26T07:15:59Repositório Institucional da UFRGS - Universidade Federal do Rio Grande do Sul (UFRGS)false
dc.title.pt_BR.fl_str_mv Investigation of indirect structural and chemical parameters of GeSi nanoparticles in a silica matrix by combined synchrotron radiation techniques
title Investigation of indirect structural and chemical parameters of GeSi nanoparticles in a silica matrix by combined synchrotron radiation techniques
spellingShingle Investigation of indirect structural and chemical parameters of GeSi nanoparticles in a silica matrix by combined synchrotron radiation techniques
Gasperini, A. A. M.
Materiais semicondutores
Crescimento de semicondutores
Nanopartículas
Análise química
Espalhamento de raios-x
Estrutura fina estendida de absorção de raios x (EXAFS)
Compostos de silício
title_short Investigation of indirect structural and chemical parameters of GeSi nanoparticles in a silica matrix by combined synchrotron radiation techniques
title_full Investigation of indirect structural and chemical parameters of GeSi nanoparticles in a silica matrix by combined synchrotron radiation techniques
title_fullStr Investigation of indirect structural and chemical parameters of GeSi nanoparticles in a silica matrix by combined synchrotron radiation techniques
title_full_unstemmed Investigation of indirect structural and chemical parameters of GeSi nanoparticles in a silica matrix by combined synchrotron radiation techniques
title_sort Investigation of indirect structural and chemical parameters of GeSi nanoparticles in a silica matrix by combined synchrotron radiation techniques
author Gasperini, A. A. M.
author_facet Gasperini, A. A. M.
Malachias, A.
Fabbris, Gilberto Fernandes Lopes
Kellermann, Guinter
Gobbi, Angelo Luiz
Avendaño Soto, E.
Azevedo, Gustavo de Medeiros
author_role author
author2 Malachias, A.
Fabbris, Gilberto Fernandes Lopes
Kellermann, Guinter
Gobbi, Angelo Luiz
Avendaño Soto, E.
Azevedo, Gustavo de Medeiros
author2_role author
author
author
author
author
author
dc.contributor.author.fl_str_mv Gasperini, A. A. M.
Malachias, A.
Fabbris, Gilberto Fernandes Lopes
Kellermann, Guinter
Gobbi, Angelo Luiz
Avendaño Soto, E.
Azevedo, Gustavo de Medeiros
dc.subject.por.fl_str_mv Materiais semicondutores
Crescimento de semicondutores
Nanopartículas
Análise química
Espalhamento de raios-x
Estrutura fina estendida de absorção de raios x (EXAFS)
Compostos de silício
topic Materiais semicondutores
Crescimento de semicondutores
Nanopartículas
Análise química
Espalhamento de raios-x
Estrutura fina estendida de absorção de raios x (EXAFS)
Compostos de silício
description The formation of GeSi nanoparticles on an SiO2 matrix is studied here by synchrotron-based techniques. The shape, average diameter and size dispersion were obtained from grazing-incidence small-angle X-ray scattering data. X-ray diffraction measurements were used to obtain crystallite sizes and composition via resonant (anomalous) measurements. By using these techniques as input for extended X-ray absorption fine structure analysis, the local composition surrounding the Ge atoms is investigated. Although the results for each of the methods above are commonly analyzed separately, the combination of such techniques leads to an improved understanding of nanoparticle structural and chemical properties. Crucial indirect parameters that cannot be quantified by other means are accessed in this work, such as local strain, the possibility of forming core–shell structures, the fraction of Ge atoms diluted in the matrix (not forming nanoparticles), the amorphous and crystalline Ge fractions, and the relative population of nanoparticles with single and multiple crystalline domains.
publishDate 2012
dc.date.issued.fl_str_mv 2012
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dc.identifier.uri.fl_str_mv http://hdl.handle.net/10183/89685
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dc.relation.ispartof.pt_BR.fl_str_mv Journal of Applied Crystallography. Copenhagen. Vol. 45, no. 1 (Feb. 2012), p. 71-84
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