Investigation of indirect structural and chemical parameters of GeSi nanoparticles in a silica matrix by combined synchrotron radiation techniques
Autor(a) principal: | |
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Data de Publicação: | 2012 |
Outros Autores: | , , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UFRGS |
Texto Completo: | http://hdl.handle.net/10183/89685 |
Resumo: | The formation of GeSi nanoparticles on an SiO2 matrix is studied here by synchrotron-based techniques. The shape, average diameter and size dispersion were obtained from grazing-incidence small-angle X-ray scattering data. X-ray diffraction measurements were used to obtain crystallite sizes and composition via resonant (anomalous) measurements. By using these techniques as input for extended X-ray absorption fine structure analysis, the local composition surrounding the Ge atoms is investigated. Although the results for each of the methods above are commonly analyzed separately, the combination of such techniques leads to an improved understanding of nanoparticle structural and chemical properties. Crucial indirect parameters that cannot be quantified by other means are accessed in this work, such as local strain, the possibility of forming core–shell structures, the fraction of Ge atoms diluted in the matrix (not forming nanoparticles), the amorphous and crystalline Ge fractions, and the relative population of nanoparticles with single and multiple crystalline domains. |
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Gasperini, A. A. M.Malachias, A.Fabbris, Gilberto Fernandes LopesKellermann, GuinterGobbi, Angelo LuizAvendaño Soto, E.Azevedo, Gustavo de Medeiros2014-03-26T01:50:56Z20120021-8898http://hdl.handle.net/10183/89685000820137The formation of GeSi nanoparticles on an SiO2 matrix is studied here by synchrotron-based techniques. The shape, average diameter and size dispersion were obtained from grazing-incidence small-angle X-ray scattering data. X-ray diffraction measurements were used to obtain crystallite sizes and composition via resonant (anomalous) measurements. By using these techniques as input for extended X-ray absorption fine structure analysis, the local composition surrounding the Ge atoms is investigated. Although the results for each of the methods above are commonly analyzed separately, the combination of such techniques leads to an improved understanding of nanoparticle structural and chemical properties. Crucial indirect parameters that cannot be quantified by other means are accessed in this work, such as local strain, the possibility of forming core–shell structures, the fraction of Ge atoms diluted in the matrix (not forming nanoparticles), the amorphous and crystalline Ge fractions, and the relative population of nanoparticles with single and multiple crystalline domains.application/pdfengJournal of Applied Crystallography. Copenhagen. Vol. 45, no. 1 (Feb. 2012), p. 71-84Materiais semicondutoresCrescimento de semicondutoresNanopartículasAnálise químicaEspalhamento de raios-xEstrutura fina estendida de absorção de raios x (EXAFS)Compostos de silícioInvestigation of indirect structural and chemical parameters of GeSi nanoparticles in a silica matrix by combined synchrotron radiation techniquesEstrangeiroinfo:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da UFRGSinstname:Universidade Federal do Rio Grande do Sul (UFRGS)instacron:UFRGSORIGINAL000820137.pdf000820137.pdfTexto completo (inglês)application/pdf1434929http://www.lume.ufrgs.br/bitstream/10183/89685/1/000820137.pdf926f7afc1fd4a33a824362dce5dc4ed8MD51TEXT000820137.pdf.txt000820137.pdf.txtExtracted Texttext/plain72354http://www.lume.ufrgs.br/bitstream/10183/89685/2/000820137.pdf.txtc98a5ca838f0af8ce35f25510d96abf3MD52THUMBNAIL000820137.pdf.jpg000820137.pdf.jpgGenerated Thumbnailimage/jpeg2035http://www.lume.ufrgs.br/bitstream/10183/89685/3/000820137.pdf.jpg0c3f4eaf7a5256786444ab7a7a5d3b50MD5310183/896852020-11-26 05:15:59.092454oai:www.lume.ufrgs.br:10183/89685Repositório de PublicaçõesPUBhttps://lume.ufrgs.br/oai/requestopendoar:2020-11-26T07:15:59Repositório Institucional da UFRGS - Universidade Federal do Rio Grande do Sul (UFRGS)false |
dc.title.pt_BR.fl_str_mv |
Investigation of indirect structural and chemical parameters of GeSi nanoparticles in a silica matrix by combined synchrotron radiation techniques |
title |
Investigation of indirect structural and chemical parameters of GeSi nanoparticles in a silica matrix by combined synchrotron radiation techniques |
spellingShingle |
Investigation of indirect structural and chemical parameters of GeSi nanoparticles in a silica matrix by combined synchrotron radiation techniques Gasperini, A. A. M. Materiais semicondutores Crescimento de semicondutores Nanopartículas Análise química Espalhamento de raios-x Estrutura fina estendida de absorção de raios x (EXAFS) Compostos de silício |
title_short |
Investigation of indirect structural and chemical parameters of GeSi nanoparticles in a silica matrix by combined synchrotron radiation techniques |
title_full |
Investigation of indirect structural and chemical parameters of GeSi nanoparticles in a silica matrix by combined synchrotron radiation techniques |
title_fullStr |
Investigation of indirect structural and chemical parameters of GeSi nanoparticles in a silica matrix by combined synchrotron radiation techniques |
title_full_unstemmed |
Investigation of indirect structural and chemical parameters of GeSi nanoparticles in a silica matrix by combined synchrotron radiation techniques |
title_sort |
Investigation of indirect structural and chemical parameters of GeSi nanoparticles in a silica matrix by combined synchrotron radiation techniques |
author |
Gasperini, A. A. M. |
author_facet |
Gasperini, A. A. M. Malachias, A. Fabbris, Gilberto Fernandes Lopes Kellermann, Guinter Gobbi, Angelo Luiz Avendaño Soto, E. Azevedo, Gustavo de Medeiros |
author_role |
author |
author2 |
Malachias, A. Fabbris, Gilberto Fernandes Lopes Kellermann, Guinter Gobbi, Angelo Luiz Avendaño Soto, E. Azevedo, Gustavo de Medeiros |
author2_role |
author author author author author author |
dc.contributor.author.fl_str_mv |
Gasperini, A. A. M. Malachias, A. Fabbris, Gilberto Fernandes Lopes Kellermann, Guinter Gobbi, Angelo Luiz Avendaño Soto, E. Azevedo, Gustavo de Medeiros |
dc.subject.por.fl_str_mv |
Materiais semicondutores Crescimento de semicondutores Nanopartículas Análise química Espalhamento de raios-x Estrutura fina estendida de absorção de raios x (EXAFS) Compostos de silício |
topic |
Materiais semicondutores Crescimento de semicondutores Nanopartículas Análise química Espalhamento de raios-x Estrutura fina estendida de absorção de raios x (EXAFS) Compostos de silício |
description |
The formation of GeSi nanoparticles on an SiO2 matrix is studied here by synchrotron-based techniques. The shape, average diameter and size dispersion were obtained from grazing-incidence small-angle X-ray scattering data. X-ray diffraction measurements were used to obtain crystallite sizes and composition via resonant (anomalous) measurements. By using these techniques as input for extended X-ray absorption fine structure analysis, the local composition surrounding the Ge atoms is investigated. Although the results for each of the methods above are commonly analyzed separately, the combination of such techniques leads to an improved understanding of nanoparticle structural and chemical properties. Crucial indirect parameters that cannot be quantified by other means are accessed in this work, such as local strain, the possibility of forming core–shell structures, the fraction of Ge atoms diluted in the matrix (not forming nanoparticles), the amorphous and crystalline Ge fractions, and the relative population of nanoparticles with single and multiple crystalline domains. |
publishDate |
2012 |
dc.date.issued.fl_str_mv |
2012 |
dc.date.accessioned.fl_str_mv |
2014-03-26T01:50:56Z |
dc.type.driver.fl_str_mv |
Estrangeiro info:eu-repo/semantics/article |
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info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10183/89685 |
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0021-8898 |
dc.identifier.nrb.pt_BR.fl_str_mv |
000820137 |
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0021-8898 000820137 |
url |
http://hdl.handle.net/10183/89685 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.ispartof.pt_BR.fl_str_mv |
Journal of Applied Crystallography. Copenhagen. Vol. 45, no. 1 (Feb. 2012), p. 71-84 |
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info:eu-repo/semantics/openAccess |
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openAccess |
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application/pdf |
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