Crystalstructure of N-(2-Cyano-1-Phenylprop-2-en-1-yl)-4-Methylbenzenesulfonamide

Detalhes bibliográficos
Autor(a) principal: Rubinger, M. M. M.
Data de Publicação: 2018
Outros Autores: Souza, R. A. C., Guilardi, S., Terra, L. R., Tavares, E. C., Ellena, J. A.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: LOCUS Repositório Institucional da UFV
Texto Completo: https://doi.org/10.1134/S0022476618050244
http://www.locus.ufv.br/handle/123456789/23785
Resumo: New allylsulfonamide is prepared in a four-step synthetic route: the Morita-Baylis-Hillman adduct prepared from benzaldehyde and acrylonitrile is acetylated using acetic anhydride and DMAP. The acetylated product reacts with DABCO displaced by the addition of 4-methylbenzenesulfonamide. The final product is characterized by high-resolution mass spectrometry, infrared, and NMR spectroscopic techniques. The X-ray crystallographic method is used to determine the crystal structure and features of the molecular structure of the compound.
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spelling Rubinger, M. M. M.Souza, R. A. C.Guilardi, S.Terra, L. R.Tavares, E. C.Ellena, J. A.2019-03-01T14:00:56Z2019-03-01T14:00:56Z2018-091573-8779https://doi.org/10.1134/S0022476618050244http://www.locus.ufv.br/handle/123456789/23785New allylsulfonamide is prepared in a four-step synthetic route: the Morita-Baylis-Hillman adduct prepared from benzaldehyde and acrylonitrile is acetylated using acetic anhydride and DMAP. The acetylated product reacts with DABCO displaced by the addition of 4-methylbenzenesulfonamide. The final product is characterized by high-resolution mass spectrometry, infrared, and NMR spectroscopic techniques. The X-ray crystallographic method is used to determine the crystal structure and features of the molecular structure of the compound.engJournal of Structural ChemistryVolume 59, Issue 5, Pages 1192–1194, September 2018Pleiades Publishing, Ltd.info:eu-repo/semantics/openAccessSynthesisX-ray crystallographic analysisAllylsulfonamideMorita-Baylis-Hillman adductCrystalstructure of N-(2-Cyano-1-Phenylprop-2-en-1-yl)-4-Methylbenzenesulfonamideinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfreponame:LOCUS Repositório Institucional da UFVinstname:Universidade Federal de Viçosa (UFV)instacron:UFVORIGINALartigo.pdfartigo.pdfTexto completoapplication/pdf360965https://locus.ufv.br//bitstream/123456789/23785/1/artigo.pdfa96d80b05d271c73faec6785aba4add6MD51LICENSElicense.txtlicense.txttext/plain; charset=utf-81748https://locus.ufv.br//bitstream/123456789/23785/2/license.txt8a4605be74aa9ea9d79846c1fba20a33MD52123456789/237852019-03-01 11:01:30.212oai:locus.ufv.br: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Repositório InstitucionalPUBhttps://www.locus.ufv.br/oai/requestfabiojreis@ufv.bropendoar:21452019-03-01T14:01:30LOCUS Repositório Institucional da UFV - Universidade Federal de Viçosa (UFV)false
dc.title.en.fl_str_mv Crystalstructure of N-(2-Cyano-1-Phenylprop-2-en-1-yl)-4-Methylbenzenesulfonamide
title Crystalstructure of N-(2-Cyano-1-Phenylprop-2-en-1-yl)-4-Methylbenzenesulfonamide
spellingShingle Crystalstructure of N-(2-Cyano-1-Phenylprop-2-en-1-yl)-4-Methylbenzenesulfonamide
Rubinger, M. M. M.
Synthesis
X-ray crystallographic analysis
Allylsulfonamide
Morita-Baylis-Hillman adduct
title_short Crystalstructure of N-(2-Cyano-1-Phenylprop-2-en-1-yl)-4-Methylbenzenesulfonamide
title_full Crystalstructure of N-(2-Cyano-1-Phenylprop-2-en-1-yl)-4-Methylbenzenesulfonamide
title_fullStr Crystalstructure of N-(2-Cyano-1-Phenylprop-2-en-1-yl)-4-Methylbenzenesulfonamide
title_full_unstemmed Crystalstructure of N-(2-Cyano-1-Phenylprop-2-en-1-yl)-4-Methylbenzenesulfonamide
title_sort Crystalstructure of N-(2-Cyano-1-Phenylprop-2-en-1-yl)-4-Methylbenzenesulfonamide
author Rubinger, M. M. M.
author_facet Rubinger, M. M. M.
Souza, R. A. C.
Guilardi, S.
Terra, L. R.
Tavares, E. C.
Ellena, J. A.
author_role author
author2 Souza, R. A. C.
Guilardi, S.
Terra, L. R.
Tavares, E. C.
Ellena, J. A.
author2_role author
author
author
author
author
dc.contributor.author.fl_str_mv Rubinger, M. M. M.
Souza, R. A. C.
Guilardi, S.
Terra, L. R.
Tavares, E. C.
Ellena, J. A.
dc.subject.pt-BR.fl_str_mv Synthesis
X-ray crystallographic analysis
Allylsulfonamide
Morita-Baylis-Hillman adduct
topic Synthesis
X-ray crystallographic analysis
Allylsulfonamide
Morita-Baylis-Hillman adduct
description New allylsulfonamide is prepared in a four-step synthetic route: the Morita-Baylis-Hillman adduct prepared from benzaldehyde and acrylonitrile is acetylated using acetic anhydride and DMAP. The acetylated product reacts with DABCO displaced by the addition of 4-methylbenzenesulfonamide. The final product is characterized by high-resolution mass spectrometry, infrared, and NMR spectroscopic techniques. The X-ray crystallographic method is used to determine the crystal structure and features of the molecular structure of the compound.
publishDate 2018
dc.date.issued.fl_str_mv 2018-09
dc.date.accessioned.fl_str_mv 2019-03-01T14:00:56Z
dc.date.available.fl_str_mv 2019-03-01T14:00:56Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv https://doi.org/10.1134/S0022476618050244
http://www.locus.ufv.br/handle/123456789/23785
dc.identifier.issn.none.fl_str_mv 1573-8779
identifier_str_mv 1573-8779
url https://doi.org/10.1134/S0022476618050244
http://www.locus.ufv.br/handle/123456789/23785
dc.language.iso.fl_str_mv eng
language eng
dc.relation.ispartofseries.pt-BR.fl_str_mv Volume 59, Issue 5, Pages 1192–1194, September 2018
dc.rights.driver.fl_str_mv Pleiades Publishing, Ltd.
info:eu-repo/semantics/openAccess
rights_invalid_str_mv Pleiades Publishing, Ltd.
eu_rights_str_mv openAccess
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dc.publisher.none.fl_str_mv Journal of Structural Chemistry
publisher.none.fl_str_mv Journal of Structural Chemistry
dc.source.none.fl_str_mv reponame:LOCUS Repositório Institucional da UFV
instname:Universidade Federal de Viçosa (UFV)
instacron:UFV
instname_str Universidade Federal de Viçosa (UFV)
instacron_str UFV
institution UFV
reponame_str LOCUS Repositório Institucional da UFV
collection LOCUS Repositório Institucional da UFV
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