Quantificação do linalol no óleo essencial da Aniba duckei Korstermans utilizando uma nova coluna capilar POLYH4-MD em Cromatografia Gasosa
Autor(a) principal: | |
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Data de Publicação: | 2003 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | por |
Título da fonte: | Repositório Institucional da UNESP |
Texto Completo: | http://dx.doi.org/10.1590/S0100-40422003000400002 http://hdl.handle.net/11449/8707 |
Resumo: | In the present work a polyurethane polymer derived from castor oil was used as stationary phase for capillary gas chromatography. The polymer was obtained by reaction of hydroxylated compound and isocynate (NCO), forming urethane. Columns of 7 m x 0,25 mm were then coated with this stationary phase (film thickness of 0,25 µm) using static coating method. The Grob test was also performed. Samples of essential oil of the Aniba duckei Korstermans was then analysed in POLYH4-MD capillary column in order to evaluate its chromatographic perfomance. The linalool was found to be the major component and has been used as compound of departure for many important syntheses. Results show that the experimental columns give higher resolution and can be employed for analysis of essentials oils. |
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Quantificação do linalol no óleo essencial da Aniba duckei Korstermans utilizando uma nova coluna capilar POLYH4-MD em Cromatografia GasosaQuantitation of linalol in the essential oil of Aniba duckei Korstermans using a new POLYH4-MD capillary column in Gas ChromatographyPOLYH4 - MD capillary columnlinaloolpolymerIn the present work a polyurethane polymer derived from castor oil was used as stationary phase for capillary gas chromatography. The polymer was obtained by reaction of hydroxylated compound and isocynate (NCO), forming urethane. Columns of 7 m x 0,25 mm were then coated with this stationary phase (film thickness of 0,25 µm) using static coating method. The Grob test was also performed. Samples of essential oil of the Aniba duckei Korstermans was then analysed in POLYH4-MD capillary column in order to evaluate its chromatographic perfomance. The linalool was found to be the major component and has been used as compound of departure for many important syntheses. Results show that the experimental columns give higher resolution and can be employed for analysis of essentials oils.Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Universidade de São Paulo Instituto de Química de São CarlosUniversidade Estadual Paulista Departamento de QuímicaUniversidade Federal do Amazonas Departamento de QuímicaUniversidade Federal do Maranhão Centro de Ciências Exatas e Tecnologia Departamento de Tecnologia QuímicaUniversidade Estadual Paulista Departamento de QuímicaSociedade Brasileira de QuímicaUniversidade de São Paulo (USP)Universidade Estadual Paulista (Unesp)Universidade Federal do Amazonas (UFAM)Universidade Federal do Maranhão (UFMA)Silva, Denise Domingos daChierice, Gilberto OrivaldoGalhiane, Mario Sergio [UNESP]Chaar, Jamal da SilvaMouchrek-Filho, Victor Elias2014-05-20T13:26:49Z2014-05-20T13:26:49Z2003-08-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article461-465application/pdfhttp://dx.doi.org/10.1590/S0100-40422003000400002Química Nova. Sociedade Brasileira de Química, v. 26, n. 4, p. 461-465, 2003.0100-4042http://hdl.handle.net/11449/870710.1590/S0100-40422003000400002S0100-40422003000400002S0100-40422003000400002.pdf3612277056838097SciELOreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPporQuímica Nova0.6460,255info:eu-repo/semantics/openAccess2024-04-29T18:17:00Zoai:repositorio.unesp.br:11449/8707Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462024-08-05T18:42:01.163197Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false |
dc.title.none.fl_str_mv |
Quantificação do linalol no óleo essencial da Aniba duckei Korstermans utilizando uma nova coluna capilar POLYH4-MD em Cromatografia Gasosa Quantitation of linalol in the essential oil of Aniba duckei Korstermans using a new POLYH4-MD capillary column in Gas Chromatography |
title |
Quantificação do linalol no óleo essencial da Aniba duckei Korstermans utilizando uma nova coluna capilar POLYH4-MD em Cromatografia Gasosa |
spellingShingle |
Quantificação do linalol no óleo essencial da Aniba duckei Korstermans utilizando uma nova coluna capilar POLYH4-MD em Cromatografia Gasosa Silva, Denise Domingos da POLYH4 - MD capillary column linalool polymer |
title_short |
Quantificação do linalol no óleo essencial da Aniba duckei Korstermans utilizando uma nova coluna capilar POLYH4-MD em Cromatografia Gasosa |
title_full |
Quantificação do linalol no óleo essencial da Aniba duckei Korstermans utilizando uma nova coluna capilar POLYH4-MD em Cromatografia Gasosa |
title_fullStr |
Quantificação do linalol no óleo essencial da Aniba duckei Korstermans utilizando uma nova coluna capilar POLYH4-MD em Cromatografia Gasosa |
title_full_unstemmed |
Quantificação do linalol no óleo essencial da Aniba duckei Korstermans utilizando uma nova coluna capilar POLYH4-MD em Cromatografia Gasosa |
title_sort |
Quantificação do linalol no óleo essencial da Aniba duckei Korstermans utilizando uma nova coluna capilar POLYH4-MD em Cromatografia Gasosa |
author |
Silva, Denise Domingos da |
author_facet |
Silva, Denise Domingos da Chierice, Gilberto Orivaldo Galhiane, Mario Sergio [UNESP] Chaar, Jamal da Silva Mouchrek-Filho, Victor Elias |
author_role |
author |
author2 |
Chierice, Gilberto Orivaldo Galhiane, Mario Sergio [UNESP] Chaar, Jamal da Silva Mouchrek-Filho, Victor Elias |
author2_role |
author author author author |
dc.contributor.none.fl_str_mv |
Universidade de São Paulo (USP) Universidade Estadual Paulista (Unesp) Universidade Federal do Amazonas (UFAM) Universidade Federal do Maranhão (UFMA) |
dc.contributor.author.fl_str_mv |
Silva, Denise Domingos da Chierice, Gilberto Orivaldo Galhiane, Mario Sergio [UNESP] Chaar, Jamal da Silva Mouchrek-Filho, Victor Elias |
dc.subject.por.fl_str_mv |
POLYH4 - MD capillary column linalool polymer |
topic |
POLYH4 - MD capillary column linalool polymer |
description |
In the present work a polyurethane polymer derived from castor oil was used as stationary phase for capillary gas chromatography. The polymer was obtained by reaction of hydroxylated compound and isocynate (NCO), forming urethane. Columns of 7 m x 0,25 mm were then coated with this stationary phase (film thickness of 0,25 µm) using static coating method. The Grob test was also performed. Samples of essential oil of the Aniba duckei Korstermans was then analysed in POLYH4-MD capillary column in order to evaluate its chromatographic perfomance. The linalool was found to be the major component and has been used as compound of departure for many important syntheses. Results show that the experimental columns give higher resolution and can be employed for analysis of essentials oils. |
publishDate |
2003 |
dc.date.none.fl_str_mv |
2003-08-01 2014-05-20T13:26:49Z 2014-05-20T13:26:49Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://dx.doi.org/10.1590/S0100-40422003000400002 Química Nova. Sociedade Brasileira de Química, v. 26, n. 4, p. 461-465, 2003. 0100-4042 http://hdl.handle.net/11449/8707 10.1590/S0100-40422003000400002 S0100-40422003000400002 S0100-40422003000400002.pdf 3612277056838097 |
url |
http://dx.doi.org/10.1590/S0100-40422003000400002 http://hdl.handle.net/11449/8707 |
identifier_str_mv |
Química Nova. Sociedade Brasileira de Química, v. 26, n. 4, p. 461-465, 2003. 0100-4042 10.1590/S0100-40422003000400002 S0100-40422003000400002 S0100-40422003000400002.pdf 3612277056838097 |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.relation.none.fl_str_mv |
Química Nova 0.646 0,255 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
461-465 application/pdf |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
dc.source.none.fl_str_mv |
SciELO reponame:Repositório Institucional da UNESP instname:Universidade Estadual Paulista (UNESP) instacron:UNESP |
instname_str |
Universidade Estadual Paulista (UNESP) |
instacron_str |
UNESP |
institution |
UNESP |
reponame_str |
Repositório Institucional da UNESP |
collection |
Repositório Institucional da UNESP |
repository.name.fl_str_mv |
Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP) |
repository.mail.fl_str_mv |
|
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1808128968044314624 |