Ethyl (E)-2-methoxyimino-2-(4-nitrobenzoyl)acetate

Detalhes bibliográficos
Autor(a) principal: Caracelli, Ignez [UNESP]
Data de Publicação: 2010
Outros Autores: Moran, Paulo J. S., Hinoue, Luciana, Zukerman-Schpector, Julio, Tiekink, Edward R. T.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UNESP
Texto Completo: http://dx.doi.org/10.1107/S1600536810001583
http://hdl.handle.net/11449/8529
Resumo: The title molecule, C(12)H(12)N(2)O(6), features an E conformation about the oxime group. The methoxyimino and ester residues are effectively coplanar with each other (r.m.s. deviation for the nine non-H atoms = 0.127 angstrom) and almost orthogonal [with dihedral angles of 99.44 (13) and - 77.85 (13)degrees, respectively] to the carbonyl and nitrophenyl groups which lie to either side of this central plane. The crystal structure is consolidated by C-H center dot center dot center dot O contacts.
id UNSP_aca806e852716e00bbb34790b954928c
oai_identifier_str oai:repositorio.unesp.br:11449/8529
network_acronym_str UNSP
network_name_str Repositório Institucional da UNESP
repository_id_str 2946
spelling Ethyl (E)-2-methoxyimino-2-(4-nitrobenzoyl)acetateThe title molecule, C(12)H(12)N(2)O(6), features an E conformation about the oxime group. The methoxyimino and ester residues are effectively coplanar with each other (r.m.s. deviation for the nine non-H atoms = 0.127 angstrom) and almost orthogonal [with dihedral angles of 99.44 (13) and - 77.85 (13)degrees, respectively] to the carbonyl and nitrophenyl groups which lie to either side of this central plane. The crystal structure is consolidated by C-H center dot center dot center dot O contacts.Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Univ Estadual Paulista, UNESP, BioMat Phys Dept, BR-17033360 Bauru, SP, BrazilUniv Estadual Campinas, Inst Quim, BR-13083970 Campinas, SP, BrazilUniv Fed Sao Carlos, Dept Chem, BR-13562905 Sao Carlos, SP, BrazilUniv Malaya, Dept Chem, Kuala Lumpur 50603, MalaysiaUniv Estadual Paulista, UNESP, BioMat Phys Dept, BR-17033360 Bauru, SP, BrazilWiley-BlackwellUniversidade Estadual Paulista (Unesp)Universidade Estadual de Campinas (UNICAMP)Universidade Federal de São Carlos (UFSCar)Univ MalayaCaracelli, Ignez [UNESP]Moran, Paulo J. S.Hinoue, LucianaZukerman-Schpector, JulioTiekink, Edward R. T.2014-05-20T13:26:28Z2014-05-20T13:26:28Z2010-02-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleO396-U2796application/pdfhttp://dx.doi.org/10.1107/S1600536810001583Acta Crystallographica Section E-structure Reports Online. Malden: Wiley-blackwell, v. 66, p. O396-U2796, 2010.1600-5368http://hdl.handle.net/11449/852910.1107/S1600536810001583WOS:000274115200234WOS000274115200234.pdfWeb of Sciencereponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengActa Crystallographica Section E: Structure Reports Online0,138info:eu-repo/semantics/openAccess2024-04-25T17:39:29Zoai:repositorio.unesp.br:11449/8529Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462024-04-25T17:39:29Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false
dc.title.none.fl_str_mv Ethyl (E)-2-methoxyimino-2-(4-nitrobenzoyl)acetate
title Ethyl (E)-2-methoxyimino-2-(4-nitrobenzoyl)acetate
spellingShingle Ethyl (E)-2-methoxyimino-2-(4-nitrobenzoyl)acetate
Caracelli, Ignez [UNESP]
title_short Ethyl (E)-2-methoxyimino-2-(4-nitrobenzoyl)acetate
title_full Ethyl (E)-2-methoxyimino-2-(4-nitrobenzoyl)acetate
title_fullStr Ethyl (E)-2-methoxyimino-2-(4-nitrobenzoyl)acetate
title_full_unstemmed Ethyl (E)-2-methoxyimino-2-(4-nitrobenzoyl)acetate
title_sort Ethyl (E)-2-methoxyimino-2-(4-nitrobenzoyl)acetate
author Caracelli, Ignez [UNESP]
author_facet Caracelli, Ignez [UNESP]
Moran, Paulo J. S.
Hinoue, Luciana
Zukerman-Schpector, Julio
Tiekink, Edward R. T.
author_role author
author2 Moran, Paulo J. S.
Hinoue, Luciana
Zukerman-Schpector, Julio
Tiekink, Edward R. T.
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Universidade Estadual Paulista (Unesp)
Universidade Estadual de Campinas (UNICAMP)
Universidade Federal de São Carlos (UFSCar)
Univ Malaya
dc.contributor.author.fl_str_mv Caracelli, Ignez [UNESP]
Moran, Paulo J. S.
Hinoue, Luciana
Zukerman-Schpector, Julio
Tiekink, Edward R. T.
description The title molecule, C(12)H(12)N(2)O(6), features an E conformation about the oxime group. The methoxyimino and ester residues are effectively coplanar with each other (r.m.s. deviation for the nine non-H atoms = 0.127 angstrom) and almost orthogonal [with dihedral angles of 99.44 (13) and - 77.85 (13)degrees, respectively] to the carbonyl and nitrophenyl groups which lie to either side of this central plane. The crystal structure is consolidated by C-H center dot center dot center dot O contacts.
publishDate 2010
dc.date.none.fl_str_mv 2010-02-01
2014-05-20T13:26:28Z
2014-05-20T13:26:28Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://dx.doi.org/10.1107/S1600536810001583
Acta Crystallographica Section E-structure Reports Online. Malden: Wiley-blackwell, v. 66, p. O396-U2796, 2010.
1600-5368
http://hdl.handle.net/11449/8529
10.1107/S1600536810001583
WOS:000274115200234
WOS000274115200234.pdf
url http://dx.doi.org/10.1107/S1600536810001583
http://hdl.handle.net/11449/8529
identifier_str_mv Acta Crystallographica Section E-structure Reports Online. Malden: Wiley-blackwell, v. 66, p. O396-U2796, 2010.
1600-5368
10.1107/S1600536810001583
WOS:000274115200234
WOS000274115200234.pdf
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Acta Crystallographica Section E: Structure Reports Online
0,138
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv O396-U2796
application/pdf
dc.publisher.none.fl_str_mv Wiley-Blackwell
publisher.none.fl_str_mv Wiley-Blackwell
dc.source.none.fl_str_mv Web of Science
reponame:Repositório Institucional da UNESP
instname:Universidade Estadual Paulista (UNESP)
instacron:UNESP
instname_str Universidade Estadual Paulista (UNESP)
instacron_str UNESP
institution UNESP
reponame_str Repositório Institucional da UNESP
collection Repositório Institucional da UNESP
repository.name.fl_str_mv Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)
repository.mail.fl_str_mv
_version_ 1803046039336255488

Registros relacionados