Controlled release fertilizer encapsulated by a κ-carrageenan hydrogel
Autor(a) principal: | |
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Data de Publicação: | 2019 |
Outros Autores: | , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Polímeros (São Carlos. Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282019000300403 |
Resumo: | Abstract The release kinetics of nitrogen and phosphorous of a granulated fertilizer, encapsulated in a κ-carrageenan-based hydrogel (CBH), was evaluated in order to determine its release mechanism given the potential this hydrogel has as coating material for controlled release fertilizers (CFRs). The effect of pH on the release properties was also investigated. The relationship between the NH4+, NO3-, and PO43- release of encapsulated fertilizers and time was determined by short- and long-term laboratory incubations. The mechanism of the release of nutrient ions was determined by comparing the release data with the zero-order, first-order, Higuchi, Hixon-Crowell and Korsmeyer-Peppas kinetic models. The findings showed that the Korsmeyer-Peppas model could be used to describe the release characteristics of the nutrients in the encapsulated fertilizers and that non-Fickian diffusion is the main release mechanism. The experimental hydrogel showed a high water retention capacity able to absorb 300 times its weight water. |
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Polímeros (São Carlos. Online) |
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Controlled release fertilizer encapsulated by a κ-carrageenan hydrogelcarrageenancontrolled release fertilizershydropolymersrelease behaviorAbstract The release kinetics of nitrogen and phosphorous of a granulated fertilizer, encapsulated in a κ-carrageenan-based hydrogel (CBH), was evaluated in order to determine its release mechanism given the potential this hydrogel has as coating material for controlled release fertilizers (CFRs). The effect of pH on the release properties was also investigated. The relationship between the NH4+, NO3-, and PO43- release of encapsulated fertilizers and time was determined by short- and long-term laboratory incubations. The mechanism of the release of nutrient ions was determined by comparing the release data with the zero-order, first-order, Higuchi, Hixon-Crowell and Korsmeyer-Peppas kinetic models. The findings showed that the Korsmeyer-Peppas model could be used to describe the release characteristics of the nutrients in the encapsulated fertilizers and that non-Fickian diffusion is the main release mechanism. The experimental hydrogel showed a high water retention capacity able to absorb 300 times its weight water.Associação Brasileira de Polímeros2019-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282019000300403Polímeros v.29 n.3 2019reponame:Polímeros (São Carlos. Online)instname:Associação Brasileira de Polímeros (ABPol)instacron:ABPO10.1590/0104-1428.02719info:eu-repo/semantics/openAccessRozo,GladysBohorques,LauraSantamaría,Johannaeng2019-10-01T00:00:00Zoai:scielo:S0104-14282019000300403Revistahttp://www.scielo.br/pohttps://old.scielo.br/oai/scielo-oai.php||revista@abpol.org.br1678-51690104-1428opendoar:2019-10-01T00:00Polímeros (São Carlos. Online) - Associação Brasileira de Polímeros (ABPol)false |
dc.title.none.fl_str_mv |
Controlled release fertilizer encapsulated by a κ-carrageenan hydrogel |
title |
Controlled release fertilizer encapsulated by a κ-carrageenan hydrogel |
spellingShingle |
Controlled release fertilizer encapsulated by a κ-carrageenan hydrogel Rozo,Gladys carrageenan controlled release fertilizers hydropolymers release behavior |
title_short |
Controlled release fertilizer encapsulated by a κ-carrageenan hydrogel |
title_full |
Controlled release fertilizer encapsulated by a κ-carrageenan hydrogel |
title_fullStr |
Controlled release fertilizer encapsulated by a κ-carrageenan hydrogel |
title_full_unstemmed |
Controlled release fertilizer encapsulated by a κ-carrageenan hydrogel |
title_sort |
Controlled release fertilizer encapsulated by a κ-carrageenan hydrogel |
author |
Rozo,Gladys |
author_facet |
Rozo,Gladys Bohorques,Laura Santamaría,Johanna |
author_role |
author |
author2 |
Bohorques,Laura Santamaría,Johanna |
author2_role |
author author |
dc.contributor.author.fl_str_mv |
Rozo,Gladys Bohorques,Laura Santamaría,Johanna |
dc.subject.por.fl_str_mv |
carrageenan controlled release fertilizers hydropolymers release behavior |
topic |
carrageenan controlled release fertilizers hydropolymers release behavior |
description |
Abstract The release kinetics of nitrogen and phosphorous of a granulated fertilizer, encapsulated in a κ-carrageenan-based hydrogel (CBH), was evaluated in order to determine its release mechanism given the potential this hydrogel has as coating material for controlled release fertilizers (CFRs). The effect of pH on the release properties was also investigated. The relationship between the NH4+, NO3-, and PO43- release of encapsulated fertilizers and time was determined by short- and long-term laboratory incubations. The mechanism of the release of nutrient ions was determined by comparing the release data with the zero-order, first-order, Higuchi, Hixon-Crowell and Korsmeyer-Peppas kinetic models. The findings showed that the Korsmeyer-Peppas model could be used to describe the release characteristics of the nutrients in the encapsulated fertilizers and that non-Fickian diffusion is the main release mechanism. The experimental hydrogel showed a high water retention capacity able to absorb 300 times its weight water. |
publishDate |
2019 |
dc.date.none.fl_str_mv |
2019-01-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282019000300403 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282019000300403 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/0104-1428.02719 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Associação Brasileira de Polímeros |
publisher.none.fl_str_mv |
Associação Brasileira de Polímeros |
dc.source.none.fl_str_mv |
Polímeros v.29 n.3 2019 reponame:Polímeros (São Carlos. Online) instname:Associação Brasileira de Polímeros (ABPol) instacron:ABPO |
instname_str |
Associação Brasileira de Polímeros (ABPol) |
instacron_str |
ABPO |
institution |
ABPO |
reponame_str |
Polímeros (São Carlos. Online) |
collection |
Polímeros (São Carlos. Online) |
repository.name.fl_str_mv |
Polímeros (São Carlos. Online) - Associação Brasileira de Polímeros (ABPol) |
repository.mail.fl_str_mv |
||revista@abpol.org.br |
_version_ |
1754212590894972928 |