Controlled release fertilizer encapsulated by a κ-carrageenan hydrogel

Detalhes bibliográficos
Autor(a) principal: Rozo,Gladys
Data de Publicação: 2019
Outros Autores: Bohorques,Laura, Santamaría,Johanna
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Polímeros (São Carlos. Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282019000300403
Resumo: Abstract The release kinetics of nitrogen and phosphorous of a granulated fertilizer, encapsulated in a κ-carrageenan-based hydrogel (CBH), was evaluated in order to determine its release mechanism given the potential this hydrogel has as coating material for controlled release fertilizers (CFRs). The effect of pH on the release properties was also investigated. The relationship between the NH4+, NO3-, and PO43- release of encapsulated fertilizers and time was determined by short- and long-term laboratory incubations. The mechanism of the release of nutrient ions was determined by comparing the release data with the zero-order, first-order, Higuchi, Hixon-Crowell and Korsmeyer-Peppas kinetic models. The findings showed that the Korsmeyer-Peppas model could be used to describe the release characteristics of the nutrients in the encapsulated fertilizers and that non-Fickian diffusion is the main release mechanism. The experimental hydrogel showed a high water retention capacity able to absorb 300 times its weight water.
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spelling Controlled release fertilizer encapsulated by a κ-carrageenan hydrogelcarrageenancontrolled release fertilizershydropolymersrelease behaviorAbstract The release kinetics of nitrogen and phosphorous of a granulated fertilizer, encapsulated in a κ-carrageenan-based hydrogel (CBH), was evaluated in order to determine its release mechanism given the potential this hydrogel has as coating material for controlled release fertilizers (CFRs). The effect of pH on the release properties was also investigated. The relationship between the NH4+, NO3-, and PO43- release of encapsulated fertilizers and time was determined by short- and long-term laboratory incubations. The mechanism of the release of nutrient ions was determined by comparing the release data with the zero-order, first-order, Higuchi, Hixon-Crowell and Korsmeyer-Peppas kinetic models. The findings showed that the Korsmeyer-Peppas model could be used to describe the release characteristics of the nutrients in the encapsulated fertilizers and that non-Fickian diffusion is the main release mechanism. The experimental hydrogel showed a high water retention capacity able to absorb 300 times its weight water.Associação Brasileira de Polímeros2019-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282019000300403Polímeros v.29 n.3 2019reponame:Polímeros (São Carlos. Online)instname:Associação Brasileira de Polímeros (ABPol)instacron:ABPO10.1590/0104-1428.02719info:eu-repo/semantics/openAccessRozo,GladysBohorques,LauraSantamaría,Johannaeng2019-10-01T00:00:00Zoai:scielo:S0104-14282019000300403Revistahttp://www.scielo.br/pohttps://old.scielo.br/oai/scielo-oai.php||revista@abpol.org.br1678-51690104-1428opendoar:2019-10-01T00:00Polímeros (São Carlos. Online) - Associação Brasileira de Polímeros (ABPol)false
dc.title.none.fl_str_mv Controlled release fertilizer encapsulated by a κ-carrageenan hydrogel
title Controlled release fertilizer encapsulated by a κ-carrageenan hydrogel
spellingShingle Controlled release fertilizer encapsulated by a κ-carrageenan hydrogel
Rozo,Gladys
carrageenan
controlled release fertilizers
hydropolymers
release behavior
title_short Controlled release fertilizer encapsulated by a κ-carrageenan hydrogel
title_full Controlled release fertilizer encapsulated by a κ-carrageenan hydrogel
title_fullStr Controlled release fertilizer encapsulated by a κ-carrageenan hydrogel
title_full_unstemmed Controlled release fertilizer encapsulated by a κ-carrageenan hydrogel
title_sort Controlled release fertilizer encapsulated by a κ-carrageenan hydrogel
author Rozo,Gladys
author_facet Rozo,Gladys
Bohorques,Laura
Santamaría,Johanna
author_role author
author2 Bohorques,Laura
Santamaría,Johanna
author2_role author
author
dc.contributor.author.fl_str_mv Rozo,Gladys
Bohorques,Laura
Santamaría,Johanna
dc.subject.por.fl_str_mv carrageenan
controlled release fertilizers
hydropolymers
release behavior
topic carrageenan
controlled release fertilizers
hydropolymers
release behavior
description Abstract The release kinetics of nitrogen and phosphorous of a granulated fertilizer, encapsulated in a κ-carrageenan-based hydrogel (CBH), was evaluated in order to determine its release mechanism given the potential this hydrogel has as coating material for controlled release fertilizers (CFRs). The effect of pH on the release properties was also investigated. The relationship between the NH4+, NO3-, and PO43- release of encapsulated fertilizers and time was determined by short- and long-term laboratory incubations. The mechanism of the release of nutrient ions was determined by comparing the release data with the zero-order, first-order, Higuchi, Hixon-Crowell and Korsmeyer-Peppas kinetic models. The findings showed that the Korsmeyer-Peppas model could be used to describe the release characteristics of the nutrients in the encapsulated fertilizers and that non-Fickian diffusion is the main release mechanism. The experimental hydrogel showed a high water retention capacity able to absorb 300 times its weight water.
publishDate 2019
dc.date.none.fl_str_mv 2019-01-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282019000300403
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282019000300403
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/0104-1428.02719
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Associação Brasileira de Polímeros
publisher.none.fl_str_mv Associação Brasileira de Polímeros
dc.source.none.fl_str_mv Polímeros v.29 n.3 2019
reponame:Polímeros (São Carlos. Online)
instname:Associação Brasileira de Polímeros (ABPol)
instacron:ABPO
instname_str Associação Brasileira de Polímeros (ABPol)
instacron_str ABPO
institution ABPO
reponame_str Polímeros (São Carlos. Online)
collection Polímeros (São Carlos. Online)
repository.name.fl_str_mv Polímeros (São Carlos. Online) - Associação Brasileira de Polímeros (ABPol)
repository.mail.fl_str_mv ||revista@abpol.org.br
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