Crystal structure of 5-O-benzoyl-2,3-O-isopropylidene- D-ribono-1,4-lactone

Detalhes bibliográficos
Autor(a) principal: Bortoluzzi, Adailton João
Data de Publicação: 2017
Outros Autores: Silveira, Gustavo Pozza, Sá, Marcus Mandolesi
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UFRGS
Texto Completo: http://hdl.handle.net/10183/159546
Resumo: In the title compound, C15H16O6, obtained from the acylation reaction between 2,3-O-isopropylidene-d-ribono-1,4-lactone and benzoyl chloride, the known absolute configuration for the lactone moiety of the ester substituent has been confirmed. The five-membered rings of the bicyclic lactone–dioxolane moiety both show envelope conformations and form a dihedral angle of 19.82 (7) between the lactone ring and the benzene ring. In the crystal, molecules of the acylated sugar are linked by very weak intermolecular C—H O interactions, forming a three-dimensional network.
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spelling Bortoluzzi, Adailton JoãoSilveira, Gustavo PozzaSá, Marcus Mandolesi2017-06-14T02:33:51Z20172056-9890http://hdl.handle.net/10183/159546001015011In the title compound, C15H16O6, obtained from the acylation reaction between 2,3-O-isopropylidene-d-ribono-1,4-lactone and benzoyl chloride, the known absolute configuration for the lactone moiety of the ester substituent has been confirmed. The five-membered rings of the bicyclic lactone–dioxolane moiety both show envelope conformations and form a dihedral angle of 19.82 (7) between the lactone ring and the benzene ring. In the crystal, molecules of the acylated sugar are linked by very weak intermolecular C—H O interactions, forming a three-dimensional network.application/pdfengActa crystallographica section E: crystallographic communications. Chester. Vol. E73, no. 3 (Mar. 2017), p. 407-409AcilaçãoEstrutura cristalinaInteração intermolecularDinâmica molecularCrystal structure of 5-O-benzoyl-2,3-O-isopropylidene- D-ribono-1,4-lactoneEstrangeiroinfo:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da UFRGSinstname:Universidade Federal do Rio Grande do Sul (UFRGS)instacron:UFRGSORIGINAL001015011.pdf001015011.pdfTexto completo (inglês)application/pdf376066http://www.lume.ufrgs.br/bitstream/10183/159546/1/001015011.pdfa2cc7428b03e8e7e981d3ee7391ba411MD51TEXT001015011.pdf.txt001015011.pdf.txtExtracted Texttext/plain20433http://www.lume.ufrgs.br/bitstream/10183/159546/2/001015011.pdf.txt11233ebf196b20c3aec6fa28e258fb2bMD52THUMBNAIL001015011.pdf.jpg001015011.pdf.jpgGenerated Thumbnailimage/jpeg1734http://www.lume.ufrgs.br/bitstream/10183/159546/3/001015011.pdf.jpgf730542692a546e8e6726dcc2f894e15MD5310183/1595462018-10-23 09:09:45.13oai:www.lume.ufrgs.br:10183/159546Repositório de PublicaçõesPUBhttps://lume.ufrgs.br/oai/requestopendoar:2018-10-23T12:09:45Repositório Institucional da UFRGS - Universidade Federal do Rio Grande do Sul (UFRGS)false
dc.title.pt_BR.fl_str_mv Crystal structure of 5-O-benzoyl-2,3-O-isopropylidene- D-ribono-1,4-lactone
title Crystal structure of 5-O-benzoyl-2,3-O-isopropylidene- D-ribono-1,4-lactone
spellingShingle Crystal structure of 5-O-benzoyl-2,3-O-isopropylidene- D-ribono-1,4-lactone
Bortoluzzi, Adailton João
Acilação
Estrutura cristalina
Interação intermolecular
Dinâmica molecular
title_short Crystal structure of 5-O-benzoyl-2,3-O-isopropylidene- D-ribono-1,4-lactone
title_full Crystal structure of 5-O-benzoyl-2,3-O-isopropylidene- D-ribono-1,4-lactone
title_fullStr Crystal structure of 5-O-benzoyl-2,3-O-isopropylidene- D-ribono-1,4-lactone
title_full_unstemmed Crystal structure of 5-O-benzoyl-2,3-O-isopropylidene- D-ribono-1,4-lactone
title_sort Crystal structure of 5-O-benzoyl-2,3-O-isopropylidene- D-ribono-1,4-lactone
author Bortoluzzi, Adailton João
author_facet Bortoluzzi, Adailton João
Silveira, Gustavo Pozza
Sá, Marcus Mandolesi
author_role author
author2 Silveira, Gustavo Pozza
Sá, Marcus Mandolesi
author2_role author
author
dc.contributor.author.fl_str_mv Bortoluzzi, Adailton João
Silveira, Gustavo Pozza
Sá, Marcus Mandolesi
dc.subject.por.fl_str_mv Acilação
Estrutura cristalina
Interação intermolecular
Dinâmica molecular
topic Acilação
Estrutura cristalina
Interação intermolecular
Dinâmica molecular
description In the title compound, C15H16O6, obtained from the acylation reaction between 2,3-O-isopropylidene-d-ribono-1,4-lactone and benzoyl chloride, the known absolute configuration for the lactone moiety of the ester substituent has been confirmed. The five-membered rings of the bicyclic lactone–dioxolane moiety both show envelope conformations and form a dihedral angle of 19.82 (7) between the lactone ring and the benzene ring. In the crystal, molecules of the acylated sugar are linked by very weak intermolecular C—H O interactions, forming a three-dimensional network.
publishDate 2017
dc.date.accessioned.fl_str_mv 2017-06-14T02:33:51Z
dc.date.issued.fl_str_mv 2017
dc.type.driver.fl_str_mv Estrangeiro
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dc.identifier.uri.fl_str_mv http://hdl.handle.net/10183/159546
dc.identifier.issn.pt_BR.fl_str_mv 2056-9890
dc.identifier.nrb.pt_BR.fl_str_mv 001015011
identifier_str_mv 2056-9890
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url http://hdl.handle.net/10183/159546
dc.language.iso.fl_str_mv eng
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dc.relation.ispartof.pt_BR.fl_str_mv Acta crystallographica section E: crystallographic communications. Chester. Vol. E73, no. 3 (Mar. 2017), p. 407-409
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